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Effect of adding methods of metallic phase on microstructure and thermal shock resistance of Ni/(90NiFe_2O_4-10NiO) cermets

Effect of adding methods of metallic phase on microstructure and thermal shock resistance of Ni/(90NiFe_2O_4-10NiO) cermets
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摘要 Ball mixing and electroless plating were respectively used as the adding methods of metallic phase to prepare Ni/(90NiFe2O4-10NiO) cermets for the inert anode in aluminum electrolysis. The microstructure and thermal shock resistance of cermet samples were studied. The results show that, for the samples prepared by ball mixing method, aggregation of metallic phase is found in either the green blocks or sintered samples and the extent of aggregation increases with the increase of metal content. For 6.5Ni/(90NiFe2O4-10NiO) cermets prepared with electroless plating method, the homogeneous and fine metallic particles are found in either the green compacts or sintered samples, but the relative density and thermal shock residual strength decrease by 3% and 28%-58% respectively, compared with samples prepared with ball mixing method. Ball mixing and electroless plating were respectively used as the adding methods of metallic phase to prepare Ni/(90NiFe2O4-10NiO) cermets for the inert anode in aluminum electrolysis. The microstructure and thermal shock resistance of cermet samples were studied. The results show that, for the samples prepared by ball mixing method, aggregation of metallic phase is found in either the green blocks or sintered samples and the extent of aggregation increases with the increase of metal content. For 6.5Ni/(90NiFe2O4-10NiO) cermets prepared with electroless plating method, the homogeneous and fine metallic particles are found in either the green compacts or sintered samples, but the relative density and thermal shock residual strength decrease by 3% and 28%-58% respectively, compared with samples prepared with ball mixing method.
出处 《中国有色金属学会会刊:英文版》 EI CSCD 2007年第4期681-685,共5页 Transactions of Nonferrous Metals Society of China
基金 Project(50474051) supported by the National Natural Science Foundation of China Project(2005CB623703) supported by the National Basic Research Program of China Project(03JJY3080) supported by the Natural Science Foundation of Hunan Province, China
关键词 电镀 金属陶瓷 微观结构 抗热震性 惰性阳极 铝电解 Ni/(90NiFe2O4-10NiO) cermets microstructure thermal shock resistance inert anode aluminum electrolysis
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二级参考文献7

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