摘要
固体酸是有机合成中能够替代硫酸的良好催化剂。评述了磺酸、无机盐、固体超强酸、杂多酸和分子筛等固体酸催化合成乙酸环己酯的方法。认为甲烷磺酸盐、氨基磺酸、强酸性阳离子交换树脂、结晶硫酸氢钠、固体超强酸和杂多酸适合催化合成乙酸环己酯。
Solid acid is a good catalyst that can be a substitute for sulpnuric acid in organic synthesis. Tne synthetic methods of cyclohexyl acetate catalyzed by solid acids such as sulfonic acids, inorganic salts, solid super acid, heteropoly acid, molecular sieve, etc are reviewed. The methyl sulfonate, amino sulfonic acid, strongly acidic cation-exchange resin, sodium bisulfate monohydrate, solid super acid, heteropoly acid are suitable for catalytic synthesis of cylohexyl acetate.
出处
《化学推进剂与高分子材料》
CAS
2007年第5期28-31,共4页
Chemical Propellants & Polymeric Materials
关键词
乙酸环己酯
合成
固体酸
催化
cyclohexyl acetate
synthesis
solid acid
catalysis
