摘要
综述了离子液体载催化剂和载试剂在有机合成中的应用进展.离子液体载催化剂是针对离子液体中催化剂难以回收利用的问题提出来的,它不仅可以实现均相催化,而且反应产物容易分离,催化剂可以循环使用.离子液体载有机试剂合成,又称为离子液体相有机合成,具有固相反应产物纯度高和液相反应反应快的优点.在离子液体载无机试剂的反应中,反应物毒性降低,反应条件温和,产物选择性好.
The advances of ionic liquid-anchored catalyst and ionic liquid-anchored reagent in organic synthesis are reviewed. Ionic liquid-anchored catalyst, which emerged due to the difficult isolation and recycling of catalyst in ionic liquids, cherished the merits of high catalytic activity as homogeneous catalysis and ease of catalyst recycle as multiple phase catalysis. Ionic liquid-anchored organic reagent synthesis, also called ionic liquid phase organic synthesis, had advantages of high purity of product as solid phase organic synthesis and high reaction rate as liquid phase organic synthesis. The alleviation of toxicity of inorganic reagents, high selectivity and mild reaction conditions were always explored in ionic liquid-anchored inorganic reagent synthesis.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2007年第10期1236-1243,共8页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(No.20576026)
河北省科技攻关计划(No.04213036)
石家庄市科技局招标项目(No.05907371A-7)
河北科技大学博士科研启动基金(No.QD200518)
河北科技大学校立基金(No.XL2006021)
河北科技大学杰出青年基金
河北省环境工程重点学科经费资助项目
关键词
离子液体
有机合成
应用
催化剂
试剂
ionic liquid
organic synthesis
application
catalyst
reagent
