摘要
由五氯化磷和氯化铵合成了六氯环三磷腈(Ⅰ),通过亲和取代反应由苯胺和Ⅰ合成了六(苯胺基)环三磷腈(Ⅱ),并对化合物Ⅰ和Ⅱ进行了元素分析,IR谱和质谱表征;用化合物Ⅱ与ABS树脂共混制备了阻燃ABS树脂,测试了其氧指数和力学性能等指标。发现化合物Ⅱ的加入,其氧指数得到提高且改善了ABS树脂的力学性能。
Hexachlorocyclotriphosphazene（Ⅰ） was synthesized with pentachloride and ammonium chloride, then we synthesized hexa（aniline）cyclotriphosphazene（Ⅱ）by Ⅰ reacting with aniline through nucleophilic substitution. Compound Ⅰ,Ⅱ was characterized by MS spectra, IR spectra, elementary composition. Using Ⅱ , we prepared fire-resistant ABS resin and the limited oxygen index （LOI） and other mechanical properties were tested. It was found that LOI rose and the me chanical properties were improved.
出处
《化工新型材料》
CAS
CSCD
北大核心
2007年第9期75-76,共2页
New Chemical Materials
关键词
六(苯胺基)环三磷腈
ABS树脂
力学性能
氧指数
hexa（aniline） cyclotriphosphazene, ABS resin, mechanical property,limited oxygen index
