摘要
利用微波技术合成了配合物[Gd2(Gly)6(H2O)4](ClO4)6(H2O)5,进行了化学成分分析、红外表征和热重分析.应用X衍射仪测定其晶体结构,该晶体为一维链结构,属三斜晶系,P?1空间群,晶胞参数:a=1.1569(17)nm,b=1.4138(2)nm,c=1.5642(2)nm,α=96.910(2)°,β=102.735(2)°,γ=105.512(2)°,V=2.3606(6)nm3,Z=2,Dc=2.144g?cm-3.采用精密溶解-反应量热计,通过设计热化学循环,计算出了该配合物的标准摩尔生成焓为-(7960.73±3.23)kJ?mol-1.
The complex [Gd2（Gly）6（H2O）4]（ClO4）6（H2O）5 was synthesized by a microwave technology characterized by IR spectra and a TG-DTG technique. The crystal structure of the complex was determined by an X-ray diffraction method. The crystal is a 1D chain structure, which belongs to a triclinic system with space group P1^-, and cell parameters： a=1.1569（17）nm,b=1.4138（2）nm,c=1.5642（2）nm,α=96.910（2）°,β=102.735（2）°,γ=105.512（2）°,V=2.3606（6）nm^3,Z=2,and Dc=2.144g·cm^-3. By isoperibol solution-reaction calorimetry, the standard molar enthalpy of formation of the complex was determined to be -（7960.73 ± 3.23） kJ·mol^-1.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
2007年第20期2349-2355,共7页
Acta Chimica Sinica
基金
国家自然科学基金(No.20373072)资助项目.
关键词
高氯酸钆
甘氨酸
配合物
晶体结构
标准摩尔生成焓
gadolinium perchlorate
glycine
complex
crystal structure
standard molar enthalpy of formation
