期刊文献+

离子液体在绿色催化和清洁合成中应用的进展 被引量:31

Advances of Ionic Liquid Application in Green Catalysis and Clean Synthesis
下载PDF
导出
摘要 综述了近年来离子液体在绿色催化和清洁合成中应用的研究进展;对离子液体的均相催化、离子液体的固载化、离子液体-超临界CO2(或离子液体-水)的两相过程、离子液体与其他技术的集成以及离子液体的工业化进程进行了简要介绍;对未来离子液体在绿色催化中的研究方向(新的、功能特定、环境更加友好且价格低廉的离子液体的合成;技术的集成;生物催化;离子液体的固载化;与离子液体相关的反应器和反应工艺的建立等)进行了展望。 Recent researches of ionic liquid and its application in green catalysis and clean synthesis were reviewed, including homogeneous catalysis in ionic liquid, immobilization of ionic liquid, two - phase process of ionic liquid - supercritical CO2 or ionic liquid - H2O systems, integration of ionic liquid with other technologies and industrialization of ionic liquid application. Research trends of ionic liquid application in green catalysis were discussed, namely synthesis of ionic liquid with specific function, lower cost and environmental friendly, biocatalysis in ionic liquid, immobilization of ionic liquid, developing of process involving ionic liquid and relevant reactor.
出处 《石油化工》 EI CAS CSCD 北大核心 2007年第10期975-984,共10页 Petrochemical Technology
基金 国家自然科学基金项目(20533080 20225309)
关键词 离子液体 均相催化 固载化 两相过程 绿色催化 清洁合成 ionic liquid homogeneous catalysis immobilization two - phase process green catalysis clean synthesis
  • 相关文献

参考文献44

  • 1Blanchard L A, Hancu D, Beckman E J, et al. Green Processing Using Ionic Liquids and CO2. Nature, 1999, 399:28 -29
  • 2Welton T. Room - Temperature Ionic Liquids. Solvents for Synthesis and Catalysis. Chem Rev, 1999, 99:2 071 -2 083
  • 3Wasserscheid P, Keim W. Ionic Liquids : New Solutions for Transition Metal Catalysis. Angew Chem Int Ed, 2000, 39 : 3 772 - 3 789
  • 4Dupont J, de Souza R F, Suarez P A Z. Ionic Liquid (Molten Salt) Phase Organometallic Catalysis. Chem Rev, 2002, 102: 3 667 -3 692
  • 5Rogers R D, Seddon K R. Ionic Liquids - Solvents of the Future? Science, 2003, 302: 792- 793
  • 6Olah G A, Mathew T, Goeppert A, et al. Ionic Liquid and Solid HF Equivalent Amine - Poly ( Hydrogen Fluoride ) Complexes Effecting Efficient Environmentally Friendly Isobutane -Isobutylene Alkylation. J Am Chem Soc, 2005, 127 : 5 964 - 5 969
  • 7Gui Jianzhou, Ban Hongyan, Cong Xiaohui, et al. Selective Alkylation of Phenol with tert - Butyl Alcohol Catalyzed by Bronsted Acidic Imidazolium Salts. J Mol Catal A : Chem, 2005, 225 : 27 - 31
  • 8Peng Jiajian, Deng Youquan. Catalytic Beckmann Rearrangement of Ketoximes in Ionic Liquids. Tetrahedron Lett, 2001 , 42:403-405
  • 9Du Zhengyin, Li Zhuopeng, Guo Shu, et al. Investigation of Physicochemical Properties of Lactam - Based Bronsted Acidic Ionic Liquids. J Phys Chem B, 2005, 109:19 542 - 19 546
  • 10Guo Shu, Du Zhengyin, Zhang Shiguo, et al. Clean Beckmann Rearrangement of Cyclohexanone Oxime in Caprolactam - Based Bronsted Acidic Ionic Liquids. Green Chem, 2006, 8:296 -300

同被引文献511

引证文献31

二级引证文献128

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部