摘要
氯化锌、三(2-氨基乙基)胺及四氟硼酸钠在甲醇介质中反应,合成单核锌配合物{[(tren)ZnCl]BF4},用IR和1H NMR等手段对该化合物的结构进行表征.单晶x衍射法测得其晶体结构为单斜晶系,空间点群为P2(1)/c,晶体学参数为a=1.068 0(3)nm,b=1.153 2(3)nm,c=1.103 4(3)nm,α=90.00°,β=102.453°,γ=90.00°,V=1.327 0(7)nm3,Dc=1.671 g/cm3,Z=4,F(000)=680,μ=2.083 mm-1.
A new mononuclear complex {E（tren）ZnC1-]BF4 } was synthesized based on the reaction of zinc chloride, sodium tetrafluoroborate and tren （tris （2-aminoethyl） amine ） in methanol medium. Its struc- ture was characterized with IR spectrum, ^1H NMR. The crystal structure of the compound was also determined with X-ray mono-crystal diffraction. The crystal was of monoclinic system with space group P2 （1）/ c, and crystallographic data of the compound were a： 1.068 0 （3） nm, b=1. 153 2 （3） nm,b=1. 103 4 （3） nm,a=90.00°,β=102. 4530°,7=.90. 0°,V=1. 327 0（7） nm^3 ,Dε=1. 671 g/cm^3 ,Z=4,F（000）=680, μ= 2.083 mm^-1.
出处
《兰州理工大学学报》
CAS
北大核心
2007年第5期73-75,共3页
Journal of Lanzhou University of Technology
