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溶胶凝胶法制备钛酸锶钡(Ba_(1-x)Sr_x)TiO_3陶瓷及其介电性能的研究 被引量:13

Preparation and dielectric characterization of Ba_(1-x)Sr_xTiO_3 ceramics by sol-gel technique
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摘要 采用硝酸钡、硝酸锶、钛酸丁酯和柠檬酸为原料的配合物溶胶凝胶方法制备了(Ba1-xSrx)TiO3(BST)陶瓷。实验结果表明,BST粉体合成温度及烧结温度分别为700及1250℃,均低于传统工艺的相应温度。Sr含量x≥0.40,(Ba1-xSrx)TiO3陶瓷的相结构为立方钙钛矿相;Sr含量x<0.40,(Ba1-xSrx)TiO3陶瓷的相结构为四方钙钛矿型。(Ba1-xSrx)TiO3(0.5≤x≤0.70)陶瓷的电容率随温度变化曲线,说明存在由铁电四方相到顺电立方相的相变。且随锶(Sr)的摩尔量x的增加,(Ba1-xSrx)TiO3陶瓷样品的相变温度向低温方向移动,相变温度Tc的移动关系为Tc=394.1-272.6x(K)。 The Ba1-xSrxTiO3 (BST) ceramics of various compositions were prepared by sol-gel-derived powders. The microstructure and dielectric properties of Ba1-xSrxTiO3 ceramics with X from 0.3 to 0.5 have been investigated. Experimental results showed that the synthetic temperature of Ba1-xSrxTiO3 powder is 700℃, which is much lower than that by the conventional solid-state reaction method. The Ba0.60 Sr0.40 TiO3 powder obtained is a cubical phase. The typical cubic phase structure with x≥0.4 and tetragonal phase structure with x〈0.4 in the XRD pattern of the Ba1-xSrxTiO3 ceramics sintered at 1573K. The sintering temperature of the Ba0.60Sr0.40TiO3 powder falls to 1250℃. Sr acts as substitution to replace Ba in the A site of ABO3 perovskite structure, leading to a shift of Curie temperature (To) to lower temperature with increasing Sr content. The correlation of Curie temperature (Tc) dependence of Sr content (x) for the Ba1-xSrxTiO3 ceramics can be expressed as Tc=394.1- 272.6x (K).
作者 王疆瑛 姚熹
出处 《功能材料》 EI CAS CSCD 北大核心 2007年第3期389-392,共4页 Journal of Functional Materials
基金 国家重点基础研究发展计划(973计划)资助项目(2002CB613304)
关键词 钛酸锶钡陶瓷 溶胶凝胶 介电性能 相变 barium strontium titanate sol-gel dielectric property phase transition
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  • 1Ohfuji S,Itsumi M,Akiya H.[J].Jpn J Appl Phys,1997,36:5854-5859.
  • 2Varadan V K,Jose K A,Varadan V V,et al.[J].J Relly Microwave Journal,1995,33:244-254.
  • 3Liou J W,Chiou B S.[J].Jpn J Appl Phys,1997,36(7A):4359.
  • 4Outzourhit A,et al.[J].J Mater Res,1995,10 (6):1411-1417.
  • 5Pinceloup P,Courtois C,et al.[J].J Am Ceram Soc,1999,82(11):3049-56.
  • 6Khollam Y B,Bhoraskar S V,Deshpande S B,et al.[J].Materials Letters,2003,57:1871-1879.
  • 7Kareiva A,Tautkus S,Rapalaviciute R.[J].Journal of Materials Science,1999,34:4853-4857.
  • 8Hench L L,West J K.[J].Chem Rev,1990,90(1):33-72.

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