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桂皮酸糖酯类衍生物的合成 被引量：2

Synthesis of glucosyl esters of cinnamic acid
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摘要 Four glucosyl esters(a～d) of cinnamic acid were synthesized by the reaction of cinnamic acid with O-acetylglucopyranosyl bromide,O-acetylgalactopyranosyl bromide,O-acetylxylopyranosyl bromide and O-acetylmaltopyranosyl bromide in the presence of Bu4NBr(c and d were new compounds).Their structures were confirmed by IR,1HNMR,MS and elemental analysis.The 1HNMR and IR spectra showed that they were β-isomers. Four glucosyl esters （a-d） of cinnamic acid were synthesized by the reaction of cinnamic acid with O- acetylglucopyranosyl bromide, O-acetylgalactopyranosyl bromide, O-acetylxylopyranosyl bromide and O- acetylmaltopyranosyl bromide in the presence of Bu4NBr（ c and d were new compounds）. Their structures were confirmed by IR, ^1HNMR,MS and elemental analysis. The ^1HNMR and IR spectra showed that they were 6- isomers.
作者 任磊 宋学伟 马晨 黄家锟 韩泳平
机构地区 西南民族大学化学与环境保护工程学院
出处 《化学研究与应用》 CAS CSCD 北大核心 2007年第11期1275-1277,共3页 Chemical Research and Application
基金 教育部留学回国人员科研启动基金资助项目(2004527) 西南民族大学人才引进项目(234377)
关键词 桂皮酸 糖酯 相转移催化 cinnamic acid glucosyl esters phase transfer catalysis
分类号 O629.1 [理学—有机化学]
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参考文献12

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化学研究与应用
2007年 第11期

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