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气相色谱填充柱改装成毛细管柱的研究

APPROXIMATE ANALYSIS FOR AXIAL DIFFUSION IN TUBULAR REACTOR ACCOMPANIED BY A SECOND-ORDER IRREVERSIBLE REACTION
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摘要 针对上分103型气相色谱仪,改装填充柱为毛细管柱后其性能良好,各项指标均达到同类仪器水平。 Based on the fact that real tubular reactor exhibit smaller degree of backmixing, approximate treatment for axial diffusion model in isothermal tubular reactor accompanied by a second-order irreversible reaction is carried out. Moreover, a approximate expression for calculating the conversion at reactor outlet XA,out is also derived. Advantage of approximate expression is simple for calculation compared with any other numerical methods for solution of axial diffusion model. Furthermore, the results ca1cu1ated by approximate expression are compared with shooting method.The agreement between both is satis factory for a wider range of Parameter.
出处 《四川轻化工学院学报》 1997年第2期59-65,共7页 Journal of Sichuan Institute of Light Industry and Chemical Technology
关键词 气相色谱 填充柱 毛细管柱 色谱仪 改装 tubular reactor axial diffusion approximate expression second-order irreversible reaction
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参考文献3

  • 1李成岳.管式反应器轴向扩散模型的迭代解法[J]化学反应工程与工艺,1988(01).
  • 2徐自新.微分方程近似解[M]华东化工学院出版社,1990.
  • 3陈敏恒等.化学反应工程基本原理[M]化学工业出版社,1982.

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