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配聚物{[Zn(C_4H_4O_6)(H_2O)_2]·2H_2O}_n的合成、晶体结构及光谱 被引量：1

Synthesis, structure and spectral behavior of {[Zn(C_4H_4O_6)(H_2O)_2](2H_2O}_n
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摘要 采用水热合成方法合成了1种Zn(Ⅱ)配位聚合物{[Zn(C4H4O6)(H2O)2]·2H2O}n,对该化合物的单晶进行了X-射线衍射分析,确定了结构.标题化合物是由酒石酸根作为六齿配体与Zn(Ⅱ)离子进行配位形成的具有3D无限结构的配位聚合物.同时对化合物的紫外-可见-近红外光谱、红外光谱及荧光光谱进行了测定及分析. Abstract. A complex, {[Zn（C4 H4 O6 ） （H2 O） 2 -~ （ 2H2O}n., has been synthesized by hydrothermal method and the structure is determined by single crystal X-Ray diffraction. Structural analysis reveals that the complex is an infinite three-dimensional coordination polymer constructed through μ4-tartrato bridging 8-coordinated Zn（ Ⅱ ） ion. At the same time, we have discussed the spectra of UV-Vis-NIR, FT-IR and photoluminescence.
作者 金晶 陈朋 赵力民 张丽
机构地区 辽宁师范大学化学化工学院
出处 《辽宁师范大学学报（自然科学版）》 CAS 北大核心 2007年第4期462-465,共4页 Journal of Liaoning Normal University:Natural Science Edition
基金 国家自然科学基金资助项目(20571037 90201018) 辽宁省教育厅科学技术研究项目(20060475)
关键词 Zn(Ⅱ)配位聚合物 晶体结构 光谱 Zn （ Ⅱ ） coordination polymer； crystal structure； spectral behavior
分类号 O611.2 [理学—无机化学]
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参考文献10

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共引文献10

同被引文献13

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辽宁师范大学学报（自然科学版）
2007年 第4期

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