摘要
利用荧光手段对自制的3种卟啉蒽醌化合物及其锌配合物与母体卟啉进行了研究，计算了各种化合物单重激发态的能量Es、荧光量子产率及荧光猝灭百分率．从荧光猝灭的角度证明它们确实能在光激发下进行分子内电子转移，形成分子内电荷分离态．同时探讨了有机碱的轴向配位及溶剂对PAQ化合物荧光性质的影响．
In this paper, the fluorescence spectra of porphyrinanthraquinone, porphyrin-an-thraquinone Zn(Ⅱ), and parent porphyrin were studied by means of fluorescence. The ener-gy of singlet excited state(Es), fluorescence quantum yield and quench percentage were esti-mated. It is demonstrated by the data of fluorescence quench that the intramolecular electron transfer, which leads to the formation of intramolecular electric charge separating-state, oc-curred under excitation of light indeed. In the meantime, the effects of axial coordination and solvent on fluorescence property of PAQ compounds were studied.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1997年第6期834-839,共6页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
光诱导
卟啉蒽醌
分子内电子转移
荧光法
荧光
Photoinduction, Porphyrin-anthraquinone, Intramolecular electron transfer,Fluorescence method
