摘要
The system of ZnPc-C60 ln speclal mixed organic solvents has been studled by UVVis, fluorescence and laser Raman spectra. The results prove the existence of a chargetransfer complex (CTC) by the lnteractlon between ZnPc and C60 The molar ratio of ZnPc/C60 in CTC is 2: 1. The formation equilibrium constant(K) was determined at 25 C. Mea-surements of photovoltaic effect show that ZnPc-C60 CTC leads to a rernarkable enhancementof photosensitivity comparing to that of ZnPc.
The system of ZnPc-C60 ln speclal mixed organic solvents has been studled by UVVis, fluorescence and laser Raman spectra. The results prove the existence of a chargetransfer complex (CTC) by the lnteractlon between ZnPc and C60 The molar ratio of ZnPc/C60 in CTC is 2: 1. The formation equilibrium constant(K) was determined at 25 C. Mea-surements of photovoltaic effect show that ZnPc-C60 CTC leads to a rernarkable enhancementof photosensitivity comparing to that of ZnPc.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1997年第9期1534-1536,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
福建省自然科学基金
关键词
锌酞菁
富勒烯
碳60
电荷迁移配合物
CTC
Fullerene, Zinc phthalocyanine, Charge transfer complex, Photovoltaic effect
