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1,2-丙二胺单Schiff碱镍(Ⅱ)配合物的合成与晶体结构 被引量:2

Synthesis and Crystal Structure of Nickel Complex with Singal Schiff Base of 1,2-Diaminopropane
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摘要 在室温条件下合成了N-3-羧基水杨醛-1,2-丙二胺Schiff碱单核镍配合物Ni(HCSP)2.H2O[H2CSP=N-3-羧基水杨醛-1,2-丙二胺Schiff碱].通过IR对配体及配合物的晶体结构进行了表征,并用单晶X射线衍射测定了结构.配合物属单斜晶系,空间群P2(1)/c,晶体学参数:a=0.9756(2)nm,b=1.4236(3)nm,c=1.7403(4)nm,α=90°,β=98.951(3)°,γ=90°,分子式C22H28NiN4O7,Mr=519.19,V=2.3878(8)nm3,Z=4,DC=1.430 Mg/m3,F(000)=1068,R1=0.0719,wR2=0.1844,S=0.962.化合物分子由两个一价阴离子HCSP-和一个二价镍离子组成. The title complex Ni (HCSP) 2·H2O[ H2 CSP-N-3-carboxylsalicylidene -1,2 -diaminopropane] was synthesized in methanol at room temperture. The structure was characterized by IR and single crystal X-ray diffraction, h crystallizes in monoclinic system, space group P2( 1)/c, with a = 0.975 6(2) nm, b = 1.423 6(3) nm, c = 1.7403(4) nm, α=90°,β=98.951(3)°,γ=90°, Molecular formula is C22 H28 NiN4 O7, Mr = 519.19, V = 2. 3878(8) nm3, Z = 4, Dc = 1. 430 Mg/m^3, F (000) = 1 068, R1 = 0.071 9, wR2 = 0. 184 4, S =0.962. The crystal is constructed with mononuclear units, in which the nickel atoms are coordinated by two phenolic oxygen atoms and four imine nitrogen atoms.
出处 《化学研究》 CAS 2008年第1期32-35,共4页 Chemical Research
关键词 3-羧基水杨醛 1 2-丙二胺 SCHIFF碱 晶体结构 3-carboxylsalicylaldehyde 1,2-diaminopropane Schiff base crystal struture
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