摘要
以异佛尔酮二异氰酸酯(IPDI)、聚氧化丙烯二醇(PPG-220)、二羟甲基丙酸(DMPA)、蓖麻油(CO)等为主要原料,合成交联型水性聚氨酯乳液,在此乳液中加入丙烯酰胺、引发剂(KPS),交联剂(BMA)进行自由基聚合,制备具有IPN结构的聚氨酯-聚丙烯酰胺(PU-PAAm)水凝胶。研究了(PU-PAAm)水凝胶溶胀率(SR)受pH值、温度(T)、交联剂用量等因素的影响。
Crosslinked Aqueous Polyurethane was synthesized mainly with isophorone diisocyanate(IP- D1),polyoxypropylene propylene-glycol ether (PPG-220),dimethyopropionic acid (DMPA)and castor oil (CO). AAM ,BMA ascrosslinking agent and initiator potassium persulfate (KPS) were added to form the IPN waterborne polyurethane-polyacrylamide (PU-PAAm)hydrogels.The swelling ration of the IPN hydrogel (PU-PAAm), which can act as a influence ofpH,temperature and crosslinking agent, was studied in detail.
出处
《胶体与聚合物》
2008年第1期27-30,共4页
Chinese Journal of Colloid & Polymer