摘要
研究小尺度或微区的同位素组成变化已成为地球化学分析技术发展的重要方向之一。在研制CO2激光熔蚀氧同位素制样装置的基础上,通过该装置与MAT-253质谱计联机实现了硅酸盐和氧化物矿物的氧同位素在线分析。所测样品包括NBS-28石英标样、石英玻璃,以及天然的石榴子石、锆石、橄榄石等一些难熔矿物。该装置分析的颗粒样品氧同位素分析精度为±0.22‰,最低样品量为8μmol的O2;石英玻璃原位分析的氧同位素分析精度为±0.35‰,最低样品量为7μmol的O2。这种装置和分析方法具备速度快,熔样温度高的特点,尤其适于难熔矿物。该装置可采用脉冲激光实现石英玻璃的微区原位分析,可应用于单个矿物生成环带的氧同位素研究。
The determination of isotopic composition in trace amount has become one of the major directions of development of isotopic measurements. A laser extraction system has been assembled successfully and combined with MAT-253 mass spectrometer to form a laser analytical system in this study, And the method of analyzing oxygen isotope of silicates and oxides was development. Research objects are some typical eutexia and refractory minerals, including international standard material NBS-28, quartz glass, garnet, zircon and olivine, focusing on the homogeneity and variation of oxygen isotopic composition in trace amount. The analytical precision of particle samples is ±0.22‰, and its oxygen contents for analysis are reduced to 8μMol. The analytical precision of in-situ quartz glass is ±0.35‰, and its oxygen contents for analysis are reduced to 7μMol. With this method, we can analyze very small amounts of materials with high spatial resolution, and it is also characterized by fast analytical rate and high melt temperature, especially for refractory minerals. The method can be used to investigate oxygen isotope zonation, trace amount variations on oxygen isotopic composition and oxygen isotope geochemistry in single mineral, and shows great applications about natural minerals, rocks and mantle inclusions forming conditions and the origin.
出处
《地质论评》
CAS
CSCD
北大核心
2008年第1期139-144,共6页
Geological Review
