摘要
５０℃下，测定了双十八烷基二甲基氯化铵（ＤＯＤＭＡＣ）／ｎ－Ｃ１０Ｈ２１ＯＨ／１０％ｎ－Ｃ１０Ｈ２２／Ｈ２Ｏ四元体系相图，确定了液晶区域范围，用＾２Ｈ ＮＭＲ方法，并辅以偏光显微镜照片，确定了液晶为反相六角状，用ＳＡＸＳ求出了液晶晶面间距，确定了晶面间距ｄ１与含水量ｆｗ／（１－ｆｗ）之间的线性关系，并求得圆柱形聚集体的直径ｄｓ＝４．０３５ｎｍ。
The equilibrium phase diagram for the system dioctadecyldimethylammonium chloride(DODMAC)/n - decanol/n - decane/water was determined at 50℃. The hyperfine structures of the liquid crystal phase were studied by 2H NMR,X - ray low - angle diffraction,and polarizing microscopy. All results showed that there was a reversed hexagonal liquid crystalline phase. The connection between crystalline face distance(d1) and the content of water [fw/(1 - fw)] was obtained and the diameter of the cylindrical assemble was getted to be 4.035nm.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1997年第5期491-497,共7页
Acta Chimica Sinica
基金
国家自然科学基金资助项目
