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非线性等转化率的微、积分法及其在含能材料物理化学研究中的应用 Ⅴ.基于Kooij公式的理论和数值方法 被引量:4

Differential and Integral Isoconversional Non-linear Methods and their Application in Physical Chemistry Study of Energetic Materials Ⅴ. Theory and Numerical Method Based on Kooij′s Formula
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摘要 推导了从等温和非等温数据计算表观活化能(Eα)的基于Kooij公式的8个典型非线性等转化率微、积分方程。提出了通过这8个方程计算含能材料分解反应Eα值的数值方法。 Eight typical differential and integral isoconversional non-linear equations based on Kooij's formula for computing the apparent activation energy (.Ea ) from isothermal and non-isothermal data were derived. The numerical methods of computing the value of E of decomposition reaction of energetic materials via the equations were presented.
出处 《含能材料》 EI CAS CSCD 2008年第3期290-294,308,共6页 Chinese Journal of Energetic Materials
基金 火炸药燃烧国防科技重点实验室基金(No.9140C3501010601)
关键词 物理化学 含能材料 非线性等转化率微分法 非线性等转化率积分法 分解反应 表观活化能 physical chemistry energetic materials differential isoconversional non-linear method integral isoconversional nonlinear method decomposition reaction apparent activation energy
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