摘要
推导了从等温和非等温数据计算表观活化能(Eα)的基于Kooij公式的8个典型非线性等转化率微、积分方程。提出了通过这8个方程计算含能材料分解反应Eα值的数值方法。
Eight typical differential and integral isoconversional non-linear equations based on Kooij's formula for computing the apparent activation energy (.Ea ) from isothermal and non-isothermal data were derived. The numerical methods of computing the value of E of decomposition reaction of energetic materials via the equations were presented.
出处
《含能材料》
EI
CAS
CSCD
2008年第3期290-294,308,共6页
Chinese Journal of Energetic Materials
基金
火炸药燃烧国防科技重点实验室基金(No.9140C3501010601)
关键词
物理化学
含能材料
非线性等转化率微分法
非线性等转化率积分法
分解反应
表观活化能
physical chemistry
energetic materials
differential isoconversional non-linear method
integral isoconversional nonlinear method
decomposition reaction
apparent activation energy