期刊文献+

1,2-环己二醇脱氢制邻苯二酚Ni-Na/硅藻土催化剂的研究 被引量:1

Study of Ni-Na/kieselguhr Catalysts for 1,2-Cyclohexanediol Dehydrogenation to Pyrocatechol
下载PDF
导出
摘要 采用浸渍法制备了一系列Ni-Na/硅藻土催化剂,考察了活性组分Ni含量、助剂、载体、浸渍方式等因素对催化剂活性选择性的影响。以硅藻土为载体,活性组分Ni含量30%,助剂Na含量1%~2%,采用分步浸渍法制备Ni-Na/硅藻土催化剂效果最好。环己二醇转化率可达100%,邻苯二酚选择性可达96.7%。 A series of catalysts with nickel as the active component were prepared by impregnation methods,and the influence factors such as the content of nickel,promoters and its content,carriers,impregnation methods were studied.The best catalyst was 30%(wt.)Ni-1%~2%(wt.)Na/kieselguhr catalyst which was prepared by successively impregnation.When use Ni-Na/kieselguhr catalyst,the conversion and selectivity can reach to 100% and 96.7% for 1,2-cyclohexanediol and pyrocatechol respectively.
机构地区 郑州大学化学系
出处 《香料香精化妆品》 CAS 2008年第3期4-8,共5页 Flavour Fragrance Cosmetics
关键词 邻苯二酚 Ni-Na/硅藻土 催化剂 pyrocatechol Ni-Na/kieselguhr catalyst
  • 相关文献

参考文献15

  • 1臧开保.邻苯二酚合成新工艺研究[J].农药,1993,32(3):22-24. 被引量:8
  • 2Costantini M, Laucher D. Process for hydroxylating phenols and phenol ethers: EP ,432 006 A2[P]. 1991.
  • 3Umemura S, Takamitsu N, Hamamoto T, Kuroda N. Process for preparing dihydric phenol derivatives: US, 4 078 006[P]. 1978-03 07.
  • 4Costantini M,Dromard A,Jouffret M. Process for hydroxylating of phenolic compounds: EP, 480 800 A1[P]. 1992-04-15.
  • 5Perego G,Taramasso M, Notari B. Porous crystalline syn thetic material consisting of silicon and titanium oxides: BE, 886 812[P]. 1981-06-22.
  • 6汪宝和 刘邦孚.邻苯二酚的合成及研究进展.湖北化工,1997,(1):23-26.
  • 7郑州大学..苯选择加氧制环己烯催化剂,其制备方法及调变方法和再生方法....中国,1 337 386[P]..2002-02-27..
  • 8孙利民,周彩荣,蒋登高,华勇.1,2-环己二醇及其衍生物的合成与应用[J].河南化工,2005,22(3):1-4. 被引量:10
  • 9赵淑惠,王争,刘艳丽,刘寿长.1,2-环己二醇脱氢催化剂的研究进展[J].河南化工,2007,24(3):4-6. 被引量:2
  • 10Paushkin Ya M, Buslova E M, Nizova S A. Preparation of pyrocatechol from cyclohexene[J]. Doklady Akademii Nauk SSSR, 1969, 185(1): 145-147.

二级参考文献34

  • 1杜少斌,徐元值,王瑾.杂多酸催化剂在有机合成中应用的新进展[J].精细石油化工,1994,11(2):1-10. 被引量:16
  • 2谢英男,章亚东,蒋登高.1,2-环己二醇催化脱氢制备邻苯二酚[J].精细化工,2005,22(6):478-480. 被引量:10
  • 3小甲良平 杨季秋(译).王冠醚化学[M].北京:原子能出版社,1985.21.
  • 4Halm R L,Stiel L I.AICHE. J. 1971.17.
  • 5Rihani K N,Doraiswamy I K.Ind.Eng.Chem.Fundam,1965,4.
  • 6魏文德.有机化工原料大全(第三卷)[M].北京:化学工业出版社,1988.662.
  • 7黄费安 段君健 欧景洋.1,2 -环己二醇二缩水甘油醚及其制备和用途[P].CN:1210860.1999.
  • 8Maeda Hirokazu, et al.Bull Chem. Soc. Jpn,1983,56(10):3072-3077.
  • 9Yuan T F,Stiel L I.Ind. Eng. Chem.Fundam,1970.9.
  • 10Legemaat G,Drenth W,Schmidt M,et al.Epoxidation of alkenes by hydrogen peroxide catalysed by oxo(5,10,15,20-tetraphenylporphyrinato) -molybdenum(V) complexes[J].Journal of Molecular Catalysis,1990, 62(2):119-133.

共引文献17

同被引文献42

引证文献1

二级引证文献12

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部