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二氧化锡纳米结构的光致发光及生长机制研究 被引量:5

Study on photoluminescence and growth mechanism of SnO_2 nanostructures
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摘要 通过金银合金助催的碳热蒸发方式,在单晶Si衬底上生长了几种不同形貌的SnO2纳米结构。用SEM、XRD、Raman和PL等测试技术对其形貌、结构进行了表征。结果表明:PL光谱中观察到的359和450nm两个新峰是由存在于SnO2纳米结构中的发光中心如纳米晶体或氧空位等造成的。SnO2纳米结构的生长遵从VLS机制,与反应源的不同距离所产生的温度差是造成这些纳米结构具有不同形貌的主要原因。 Several different morphologies of SnO2 nanostructures were prepared on single crystal silicon substrate by Au-Ag alloying catalyst assisted carbothermal evaporation. And its morphology and structure were characterrized by SEM, XRD, Raman and photoluminescence spectra (PL). The results show that two new peaks at 359 and 450 nm in the measured photoluminescence spectrum are observed, implying that more luminescence centers such as nanocrystals and oxygen vacancies exist in SnO2 nanostructures. The growth of SnO2 nanostructures is discussed on the basis of the vapor-liquid-solid (VLS) mechanism. Nanostructures with different morphology are determined by the different growth temperature result from the different distance away from the reaction source.
作者 王冰 徐平
出处 《电子元件与材料》 CAS CSCD 北大核心 2008年第8期52-54,64,共4页 Electronic Components And Materials
基金 深圳市微纳光子信息技术重点实验室开放基金资助项目(No.2000811)
关键词 电子技术 SnO2纳米结构 碳热蒸发 晶体生长 晶体形貌 electron technology SnO2 nanostructures carbothermal evaporation crystal growth crystal morphology
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同被引文献74

  • 1匡安龙,刘兴翀,路忠林,任尚坤,刘存业,张凤鸣,都有为.稀释磁性半导体Sn_(1-x)Mn_xO_2的室温铁磁性[J].物理学报,2005,54(6):2934-2937. 被引量:11
  • 2倪自丰,应鹏展,罗勇,戴新联,刘涛.碳热还原法制备SnO_2纳米带及其表征分析[J].无机材料学报,2007,22(4):609-612. 被引量:5
  • 3Jiarui Huanga,b,*, Kun Yua, Cuiping Gua, Muheng Zhaia, Preparation of porous flower-shaped Sn02 nanostructures and their gas-sensing property[J]. Sen- sors and Actuators B: Chemical,2010,467-474.
  • 4Qingrui Zhao, Zhengquan Li, Changzheng Wu, Xue Bai and Yi Xie Facile synthesis and optical property of SnO^2 flower-like architectures[J]. Journal of Nanoparti- cle Research, 2006, 8, 1067-1069.
  • 5B. Wang, Y.H. Yang, C.X. Wang, G.W. Yang Growth and photoluminescence of Sn0^2 nanostructures synthe- sized by Au-Ag alloying catalyst assisted carbothermal evaporation[J].Chemical Physics Letters, 2005,347-353.
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  • 9Jiarui Huanga, Kun Yua, Cuiping Gua. Preparation of porous flower- shaped SnO2 nanostructures and their gas -sensing property [ J ]. Sensors and Actuators B : Chemical, 2010:467 -474.
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