摘要
利用“河水衰减法”研究了不同培养条件下阴离子表面活性剂LAS在滇池典型入湖河口（海河口）缺氧水体中的生物降解及其动力学,探讨了温度、pH值、LAS的初始浓度、添加营养盐（NH4Cl或NaH2PO4）以及曝气等因素对LAS生物降解的影响.结果表明,在河口水体中的不同条件下,试验26 d后LAS的生物降解率都达95%以上,且降解服从二级动力学模型.温度、LAS的初始浓度、添加营养盐以及曝气均对LAS的降解有一定的影响.当水温从10℃增至25℃时,其降解速率p从0.21 d^-1增至0.90 d^-1;在连续曝气时,LAS的降解速率也由缺氧状态的0.72 d^-1提高至1.97 d^-1;LAS的初始浓度增大,其降解速率减小;添加NaH2PO4能明显地促进LAS的降解,但是NH4Cl对其降解产生抑制;不同pH值（7.05-9.44）对其降解影响不明显.
Biodegradation and degradation kinetics of anion-surfactant（LAS） in the anaerobic water of a representative inlet（Haihe River） of Lake Dianchi under different incubation conditions were studied by the ＇river die-away＇ test method.The influences of temperature,pH,initial concentration of LAS,aeration condition and added nutrients（NH4Cl or NaH2PO4） on the biodegradation of LAS in the water were investigated.The results demonstrate that LAS can be biodegraded by microorganisms in the water and that the percentage of degradation of LAS was more than 95% after 26 d.The biodegradation of LAS fit the second kinetic model.Incubation temperature,initial concentration of LAS,aeration and added nutrients（NH4Cl or NaH2PO4） can all affect the biodegradation of LAS.When the incubation temperature increased from 10℃ to 25℃,the biodegradation rate（p） of LAS increased from 0.21 d^-1 to 0.90 d^-1.The LAS degradation rate increased from 0.72 d^-1 under anaerobic condition to 1.97 d^-1 under continuous aeration condition.The increased initial concentrations of LAS lead to decrease of the biodegradation rate.NaH2PO4 accelerated the degradation of LAS but added NH4Cl instead inhibited degradation.In our experiment,pH value（7.05-9.44） had little influence on the biodegradation of LAS.
出处
《环境科学》
CAS
CSCD
北大核心
2008年第8期2189-2194,共6页
Environmental Science
基金
国家高技术研究发展计划(863)项目(2005AA60101005)
中国科学科院重要方向项目(KZCX2-YW-426)
关键词
LAS
缺氧
生物降解
河口
滇池
LAS
anaerobic
biodegradation
inlet
lake Dianchi
