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金催化剂催化氧化葡萄糖研究 被引量:1

Advanced in Gold Catalyst for Oxidation of Glucose
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摘要 采用固定化凝胶法制备1%Au/C催化剂。对Au/C催化剂的寿命进行了测试,结果显示:经过9次重复使用,每次3 h,Au/C催化剂的活性下降.同时比较了制备的Au/C和商业Pd/C催化剂对葡萄糖的液相催化氧化反应,证明Au/C催化剂明显优于Pd/C催化剂. 1% Gold on carbon was prepared by immobilizing gold sol. A test on the lifetime of the catalysts was carryed through. It showed Au/C catalyst activity declined, after nine runs Recycling use, each three hours. At the same time a comparison of the Au/C and commercial Pd/C catalyst for the liquid - phase catalytic oxidation of glucose reaction, that proved Au / C catalyst was superior Pd/C catalyst.
出处 《化工时刊》 CAS 2008年第8期22-23,共2页 Chemical Industry Times
关键词 金催化剂 葡萄糖 寿命 活性 gold catalysts glucose lifetime Activity
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参考文献6

  • 1Kirk - Othmer, "Encyclopedia of Chemical Technology," 4thed. Wiley,New York, 1993 .
  • 2Datta, R., in "Encyclopedia of Chemical Technology," Vol. 13, 4th ed. Wiley, New York, 1995.
  • 3陈先明,胡宝妹,程卫平,孟小玲.催化氧化葡萄糖制备葡萄糖酸钠和D-葡萄糖酸δ-内酯[J].化学世界,1990,31(5):205-206. 被引量:16
  • 4宋一兵,孙长勇,叶飞,陈德平,林维明.Pd/C催化剂上葡萄糖催化氧化反应[J].天然气化工—C1化学与化工,2003,28(3):56-59. 被引量:9
  • 5Tsubota S, Cunningham D A H, Bando Y. , et al. Preparation of catalysts VI” studies on surface science and catalysis [ J ] , Elsevier, Amsterdam, 1995,91:227.
  • 6Serena Biella, Laura Prati, Michele Rossi. Selective Oxidation of D - Glucose on Gold [ J ] Catalyst J. Catal. , 2002, 206 : 242 - 247

二级参考文献11

  • 1E Auer, A Freund, J Pietsch, et al.Carbons as supports for industrial precious metal catalysts [J]. Appl Catal A:General, 1998, 173:259-271.
  • 2Klaus Kohler, Roland G Heidemreich, Jurgen G E Krauter, et al. Highly active palladium/activated carbon catalysts for Heck reactions: Correlation of activity, catalyst properties, and Pd leaching [J]. Chem Eur J, 2002,8: 622-631.
  • 3J Krishna Murthy, S Chandra Shekar, V Siva Kumar, et al. Highly selective zirconium oxychloride modified Pd/C catalysts in the hydrodechlorination of dichlorodifluoromethane to difluoromethane [ J ]. Cata Comm, 2002,3 : 145 - 149.
  • 4Jonathan Phillips, John Weigle, Mordechary Herskowitz,et al. Metal particle structure: Contrasting the influences of carbons and refractory oxides [ J ]. Appl Catal A: General, 1998, 173:273-287.
  • 5Nalini Krshnankutty, Jin Li, M Albert Vannice. The effect of Pd precursor and pretreamaent on the adsorption and absorption behavior of supported Pd catalysts [J ].Appl Catal A: General, 1998, 173:137-144.
  • 6Lixin Cao, Steven L Suib, Xia Tang, et al. Thermocatalytic decomposition of dimethylphosphonate on activated carbon [J]. J Cata, 2001, 197:236 -243.
  • 7Gregor Jenzer, Michael S Schneider, Roland Wandeler,et al. Palladium-catalyzed oxidation of octyl alcohols in"Supercritical" carbon dioxide [J]. J Cam 2001,199:141- 148.
  • 8汪祖模,徐玉珮,徐寿昌,叶火先,姜昌海.水质稳定剂——葡萄糖酸钠[J]化学世界,1982(06).
  • 9杨水金,梁永光.TiSiW_(12)O_(40)/TiO_2催化合成葡萄糖酯的研究[J].精细化工,2001,18(7):408-410. 被引量:91
  • 10宋一兵,余林,孙长勇,叶飞,方奕文,林维明.Pd-Co/C催化剂上葡萄糖的催化氧化反应[J].应用化学,2002,19(10):976-980. 被引量:7

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