摘要
从吩噻嗪出发,通过取代反应引入长链烷基,Heck反应引入乙烯基π-桥和吡啶基,合成了新化合物9-己基-3,6-二[2-(2-乙烯基吡啶)]吩噻嗪(4),其结构经1H NMR,IR和MS表征。应用UV和单光子荧光光谱初步探讨了4的光学性质。
A novel organic compound, 9-hexyl-3,6-bis [ 2-（ 2-vinyl pyridine ） ] phenothiazine （ 4 ）, was synthesized from phenothiazine by substitution reaction to introduce an alkyl and Heck reaction to connect pyridine using ethylene as a π-bridge. The structure was characterized by ^1H NMR, IR and MS. The optical property of 4 was investigated by UV and single photon fluorescence spectra.
出处
《合成化学》
CAS
CSCD
2008年第5期571-573,共3页
Chinese Journal of Synthetic Chemistry
基金
国家自然科学基金资助项目(50703001
20771001)
安徽省高校青年教师科研资助计划(2007jq1019)
安徽省高校省级科技创新团队基金(2006KJ007TD)
关键词
吩噻嗪
Heek反应
光学性质
合成
phenothiazine
Heek reaction
optical property
synthesis
