期刊文献+

纳米CeO2搀杂对Ni-P化学镀层微观结构与耐蚀性能的影响 被引量:5

Effect of nano-CeO_2 doping on microstructure and corrosion of Ni-P electroless coating
下载PDF
导出
摘要 Ni-P and its nano-CeO2 doped coating were electrolessly prepared in acidic condition,and their microstructure and anti-corrosion property were studied and compared.Scanning electronic microscopy(SEM),transmission electronic microscopy(TEM),X-ray diffraction spectrometer(XRD)and differential scanning calorimeter(DSC)were used to examine surface morphology and microstructure of coatings.The results showed that Ni-P coating had partial amorphous structure mixed with nano-crystals,while the Ni-P/CeO2 coating had perfect amorphous structure.Upon heating,Ni3P precipitation and Ni crystallization took place in both coatings but at different temperatures of phase change.In addition,the Ni-P/CeO2 coating had sintered phase of NiCe2O4 spinels.The anti-corrosion property and passivity were improved in the CeO2-doped coating because it was less liable to undergo localized corrosion and had a slower corroding rate than its CeO2-free counterpart.During the co-deposition process,some Cen+(n=3,4)ions might be adsorbed to the metal/solution electrical double layer and hinder nickel deposition.Ni-P/CeO2 coating’s perfect amorphous structure was probably due to the hindered crystal-typed deposition of nickel and the promoted deposition of phosphorous. Ni-P and its nano-CeO2 doped coating were electrolessly prepared in acidic condition,and their microstructure and anti-corrosion property were studied and compared.Scanning electronic microscopy(SEM),transmission electronic microscopy(TEM),X-ray diffraction spectrometer(XRD)and differential scanning calorimeter(DSC)were used to examine surface morphology and microstructure of coatings.The results showed that Ni-P coating had partial amorphous structure mixed with nano-crystals,while the Ni-P/CeO2 coating had perfect amorphous structure.Upon heating,Ni3P precipitation and Ni crystallization took place in both coatings but at different temperatures of phase change.In addition,the Ni-P/CeO2 coating had sintered phase of NiCe2O4 spinels.The anti-corrosion property and passivity were improved in the CeO2-doped coating because it was less liable to undergo localized corrosion and had a slower corroding rate than its CeO2-free counterpart.During the co-deposition process,some Cen+(n=3,4)ions might be adsorbed to the metal/solution electrical double layer and hinder nickel deposition.Ni-P/CeO2 coating's perfect amorphous structure was probably due to the hindered crystal-typed deposition of nickel and the promoted deposition of phosphorous.
出处 《化工学报》 EI CAS CSCD 北大核心 2008年第11期2870-2874,共5页 CIESC Journal
基金 江苏省自然科学基金项目(07KJD430246)~~
关键词 搀杂 化学镀 NI-P 稀土元素 腐蚀 doping electroless deposition Ni-P rare earth element corrosion
  • 相关文献

参考文献2

二级参考文献17

  • 1JIN Huiming,FELIX A. Congrado,AROYAVE M. Hayara.Rare earth effect of yttrium on formation and property of Cr_2O_3 oxide film formed on Co-Cr binary alloy[J].Progress in Natural Science:Materials International,2006,16(1):72-77. 被引量:6
  • 2B. Kloss,M. Wenderoth,U. Glatzel,R. V?lkl. Fast Internal Oxidation of Ni–Zr–Y Alloys at Low Oxygen Pressure[J] 2004,Oxidation of Metals(3-4):239~251
  • 3Ya. S. Matychak,V. S. Pavlyna,V. M. Fedirko. Kinetics of Selective Oxidation of Chromium Steels in Oxygen-Containing Lead[J] 2003,Materials Science(5):605~614
  • 4Il Ryoung Sohn,Toshio Narita. Cracking Behavior of Cr2O3 Scales on Fe–25Cr Alloys Under Creep Deformation at 973 K in Ar Atmosphere[J] 2003,Oxidation of Metals(3-4):333~352
  • 5S. Seal,S. C. Kuiry,Leyda A. Bracho. Studies on the Surface Chemistry of Oxide Films Formed on IN-738LC Superalloy at Elevated Temperatures in Dry Air[J] 2001,Oxidation of Metals(5-6):583~603
  • 6B. Kloss,M. Wenderoth,U. Glatzel,R. V?lkl.Fast Internal Oxidation of Ni–Zr–Y Alloys at Low Oxygen Pressure[J].Oxidation of Metals (-).2004(3-4)
  • 7B. D. Vasyliv.Initiation of a Crack from the Edge of a Notch with Oblique Front in Specimens of Brittle Materials[J].Materials Science.2002(5)
  • 8A. Ul-Hamid.TEM Study of the Effect of Y on the Scale Microstructures of Cr2O3- and Al2O3-Forming Alloys[J].Oxidation of Metals (-).2002(1-2)
  • 9W. Przybilla,M. Schütze.Role of Growth Stresses on the Structure of Oxide Scales on Nickel at 800 and 900°C[J].Oxidation of Metals (-).2002(1-2)
  • 10S. Seal,S. C. Kuiry,Leyda A. Bracho.Studies on the Surface Chemistry of Oxide Films Formed on IN-738LC Superalloy at Elevated Temperatures in Dry Air[J].Oxidation of Metals (-).2001(5-6)

共引文献3

同被引文献48

引证文献5

二级引证文献27

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部