摘要
以在无溶剂条件下合成的1-氮杂-2-甲氧基-1-环庚烯为原料,加入的硫酸二甲酯的物质的量为原料1-氮杂-2-甲氧基-1-环庚烯的物质的量的1/10,95℃反应6小时,生成N-甲基己内酰胺的收率为76.3%。
With 1-aza-2-methoxyl-1-cycloheptene as material, N-methyl hexanolactam was synthesis under non-solvent, and molar ratio of dimethyl sulfate to the cycloheptene is 1：10. Reaction temperature in 95oC, and time in 6hr, the yield of N-methyl hexanolactam is 76.3%.
