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链穿梭聚合制备聚烯烃嵌段共聚物的研究进展 被引量:9

Research progresses in preparation of olefin block copolymer via chain shuttling polymerization
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摘要 综述了链穿梭聚合的最新研究进展.包括链穿梭聚合的基本原理,在制备"软、硬"嵌段共聚物、两嵌段共聚物和立体嵌段聚丙烯方面的应用,以及和其他聚合方法的比较。链穿梭聚合是一种很有前景的聚合方法。 This paper reviewed the latest advances in studies on principle and applications in preparations of "soft" and stereoblock polypropylene. A comparison was made between technologies. As a new coordination polymerization method, a polymerization process with an attractive prospect. chain shuttling polymerization, involving its basic 'hard" block copolymers, diblock copolymer and the polymerization process and other polymerization chain shuttling polymerization is widely considered
出处 《合成树脂及塑料》 EI CAS 北大核心 2008年第6期55-60,共6页 China Synthetic Resin and Plastics
基金 国家自然科学基金项目(20334030,50703044,20734002)
关键词 聚烯烃 链穿梭聚合 嵌段共聚物 链转移 配位聚合 polyolefin chain shuttling polymerization block copolymer chain transfer coordinationpolymerization
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参考文献19

  • 1Arriola D J, Carnahan E M, Hustad P D, et al. Catalytic production of olefin block copolymers via chain shuttling polymerization[J]. Science, 2006, 312(5774): 714-719.
  • 2Kemp R. How to polymerize ethylene in a highly controlled fashion[J]. Chem-Eur J, 2007, 13(10): 2764-2773.
  • 3Wang H P, Kbariwala D U, Cheung W, et al. Characterization of some new olefinie block eopolymers[J]. Maeromoleeules, 2007, 40(8): 2852-2862.
  • 4Khariwala D U, Taha A, Chum S P, et al. Crystallization kinetics of some new olefinie block eopolymers[J]. Polymer, 2008, 49(5): 1365-1375.
  • 5Hustad P D, Kuhhnan R L, Arriola D J, et al. Continuous production of ethylene-based diblock copolymers using coordinative chain transfer polymerization [J]. Maeromoleeules, 2007, 40(20): 7061-7064.
  • 6Chien J C W, Iwamoto Y, Rausch M D, et al. Homogeneous binary zirconocenium catalyst systems for propylene polymerizatinn: 1. lsotactic/atactie interfacial compatibilized polymers having thermoplastic elastomeric properties[J]. Macromolecules 1997, 30(12): 3447-3458.
  • 7Chien J C W, lwamoto Y, Rausch M D. tlomogeneous binary zirconocenium catalysts for propylene polymerization, Ⅱ. Mixtures of isospecific and syndiospecifie zirconocene systems [J]. J Polym Sci Pol Chem, 1999, 37(14): 2439-2445.
  • 8Lieber S, Brintzinger H H. Propene polymerization with catalyst mixtures containing different ansa-zirconocenes: Chain transfer to alkylaluminum cocatalysts and formation of stereoblock polymers[J]. Macromolecules, 2000, 33(25): 9192-9199.
  • 9Tynys A, Eilertsen J L, Seppala J V, et al. Propylene polymerizations with a binary metallocene system-Chain shuttling caused by trimethylaluminium between active catalyst centers [J]. J Polym Sci Pol Chem, 2007, 45(7): 1364-1376.
  • 10Boussie T R, Diamond G M, Goh C, et al. Nonconventional catalysts for isotaetie propene polymerizatinn in solution developed by using high-throughput-screening technologies [J]. Angew Chem-lnt Edit, 2006, 45(20): 3278-3283.

同被引文献136

  • 1任艳,王玉荣,刘海峰,林春清,张春庆.二甲基苯酚钾作助引发剂的烯烃阴离子调节聚合(英文)[J].中山大学学报(自然科学版),2005,44(A02):36-38. 被引量:2
  • 2梁诚.新型乙丙橡胶开发前景广阔[J].中国橡胶,2006,22(7):7-9. 被引量:4
  • 3金鹰泰,李刚,曹丽辉,蔡洪光,巴晓微,原宇平,张学全,董为民,WOO Seong-ihi,CHO Hyun-yong,CUI Li-qiang,HONG Dae-sik,JEONG Dong-wook.烯烃聚合高性能FI催化剂的进展[J].高分子通报,2006(9):37-50. 被引量:4
  • 4Sikka M,Pellegrini N N,Sehlnitt E A,et al.Modifying a polystyrene/poly(methyl methaerylate)interface with poly(sty-rene-co-methyl methacrylate) random copolymers[J].Macromolecules,1997,30(3):445-455.
  • 5szwarc M Living polymers[J].Nature,1956,178:1168-1169.
  • 6Miyamoto M,Sawamoto M,Higashimura T.Living polymerization of isobutyl vinyl ether with hydrogen iodide/iodine initiating system[J].Macromolecules,1984,17(3):265-268.
  • 7Faust R,Kennedy J P.Living carbocationic polymerization[J].Polymer Bulletin,1986,15(4):317-323.
  • 8Sawarnoto M.Modern cationic vinyl polymerization[J].Prog Polym Sci,1991,18(1):111.
  • 9Webster O W,Hertle W R,Sogah D Y,et al.A new concept for addition polymerization with organosilicon initiators[J].Am Chem Soc,1983,105(17):5706-5708.
  • 10Otsu T,Yoshida M,Tazaki T.Role of initiator-transfer agentterminator(iniferter)in radical polymerizations:polymer design by organic disulfides as iniferters[J].Macrornol Chem Rapid Commun,1982,3(2):127-132.

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