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表面活性剂与聚丙烯酰胺在油水界面的流变性 被引量:8

Interfacial Rheology Investigation of Polyacrylamide-Surfactan Interactions
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摘要 Oil -water interfacial viscosity for aqueous mixture of cetyltrimethylammonium bromide(CTAB ) and partially hydrolyzed polyarcylamide(HPAM) was studied. The results showed that interfacial viscosity dependends on the shearing rate and the hydrolysis degree of HPAM, the interfacial viscosity decreases with surfactant concentration A higher interfacial viscosity favors to enhance the emulsification stability of the aqueous mixture of HPAM and CTAB. Based on the experimental results, an explantion for CTAB-HPAM interaction at oil-water interface has been proposed. Oil -water interfacial viscosity for aqueous mixture of cetyltrimethylammonium bromide(CTAB ) and partially hydrolyzed polyarcylamide(HPAM) was studied. The results showed that interfacial viscosity dependends on the shearing rate and the hydrolysis degree of HPAM, the interfacial viscosity decreases with surfactant concentration A higher interfacial viscosity favors to enhance the emulsification stability of the aqueous mixture of HPAM and CTAB. Based on the experimental results, an explantion for CTAB-HPAM interaction at oil-water interface has been proposed.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1998年第1期88-92,共5页 Acta Physico-Chimica Sinica
基金 国家攀登计划
关键词 聚丙烯酰胺 油水界面 界面粘度 CTAB Polyacrylamide, oil-water interface,Interfacial viscosity, Cetyltrimethylammonium bromide
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参考文献2

  • 1张嘉云,Colloid Surf A,1994年,88卷,33页
  • 2赵国玺,表面活性剂物理化学,1984年,287页

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