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微波法制备Al_2O_3/NaY新型复合多孔催化材料 被引量:14

PREPARATION OF NEW POROUS MATERIALS Al 2O 3/NaY BY MICROWAVE RADIATION
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摘要 微波法制备Al2O3/NaY新型复合多孔催化材料孙德坤朱建华时吉须沁华(南京大学化学化工学院化学系,南京210093)关键词微波辐射,氧化铝,NaY沸石,表面分散,多孔复合材料分类号TQ426收稿日期:19970217.孙德坤:女,1941年生,... Al 2O 3 can be highly dispersed on NaY by using microwave radiation. The framework of NaY is still perfect. The dispersion threshold measured by XRD and IR is 0 45 ( m (Al 2O 3)/ m (NaY)), which is higher than that obtained by chemical impregnation or heating at high temperature. BET experiments have demonstrated that before dispersion threshold the adsorption capacity per unit surface (m 2) of samples for n hexane increases with the increase of Al 2O 3 loading. Besides, it is found that in NH 3 TPD experiments the acidity per unit surface (m 2) of samples increases with the increase of Al 2O 3 loading also. Interaction between Al 2O 3 and NaY is obvious after Al 2O 3 highly dispersed on NaY.
出处 《催化学报》 SCIE CAS CSCD 北大核心 1998年第1期81-84,共4页
关键词 微波辐射 氧化铝 NAY沸石 多孔复合材料 Microwave radiation, Alumina, NaY zeolite, Surface dispersion, Porous composite material
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