摘要
近几年葫芦脲和其衍生物由于其特殊的结构与性质已引起密切关注。本文综述了葫芦脲的最新研究进展,包括葫芦脲及其衍生物的分子设计与合成,与聚电解质形成主链(准)聚轮烷和侧链(准)聚轮烷,与其他有机客体分子相互作用形成轮烷和准轮烷,以及葫芦脲分子及其衍生物在囊泡、二维聚合物、色谱固定相、生物体以及药物缓释方面的最新应用。
In recent years, cucurbituril（CB [ n ] ） and its derivatives have attracted considerable attentions because of their special structures and properties. In this paper, the new development of cucurbituril is summarized, including the design and synthesis of cucurbituril and their derivatives, forming the main-chain （pseudo）polyrotaxanes and side-chain （pseudo） polyrotaxane with the polyelectrolyte, and forming （pseudo）rotaxane with other organic guest molecules. Applications of cucurbituril are also reviewed including vesicles, 2D polymers, stationary phases in chromatography, organism and drug release.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2009年第1期164-173,共10页
Progress in Chemistry
基金
国家自然科学基金项目(No.20674045)资助
关键词
葫芦脲
自组装
轮烷
有机客体分子
cucurbituril
self-assembly
rotaxane
organic guest molecules
