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Hydroformylation of methyl-3-pentenoate over a phosphite ligand modified Rh/SiO_2 catalyst 被引量:1

Hydroformylation of methyl-3-pentenoate over a phosphite ligand modified Rh/SiO_2 catalyst
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摘要 A phosphite ligand modified Rh/SiO2 catalyst has been developed for hydroformylation of internal olefins to linear aldehydes, which showed high activity and regioselectivity and could be separated easily by filtration after reaction in an autoclave. Effects of reaction temperature and syngas pressure on the performances of the catalyst in the reaction were also investigated. A phosphite ligand modified Rh/SiO2 catalyst has been developed for hydroformylation of internal olefins to linear aldehydes, which showed high activity and regioselectivity and could be separated easily by filtration after reaction in an autoclave. Effects of reaction temperature and syngas pressure on the performances of the catalyst in the reaction were also investigated.
出处 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2008年第4期351-354,共4页 天然气化学杂志(英文版)
基金 supported by the National Key Fundamental Research Development Plan("973"Plan,No.2009CB623503)
关键词 Rh/SiO2 PHOSPHITE HYDROFORMYLATION internal olefins linear aldehydes Rh/SiO2 phosphite hydroformylation internal olefins linear aldehydes
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