期刊文献+

Pd修饰TiO2光催化材料在棉织物中的应用 被引量:5

Application of Pd-TiO_2 photocatalytic material on cotton fabric
下载PDF
导出
摘要 为提高棉织物表面TiO2的光催化效果,以棉针织物为载体,纳米羟基磷灰石(HAP)为保护剂,纳米TiO2为光催化剂,实践Pd对光催化剂的表面改性,制备具有光催化功能的纺织装饰材料。并采用扫描电镜、气相色谱等测试手段,对整理剂在织物表面的沉积状况、织物对甲醛的催化降解效率等进行测试和分析。结果表明:经过Pd表面改性后,织物表面TiO2的光催化效果得到明显的改善,较改性前提高了49%,并具有很好的紫外防护效果;纳米HAP整理对织物表面光催化剂具有一定的吸附效果。 To improve the photocatalytic performance of TiO2on the surface of cotton fabric,the photocatalytically functioned decorative fabric was prepared by coating the substrate with palladiun(Pd) modified nano TiO2using HAP protective agent.The surface deposition and efficiency of the catalytic degradation of formaldehyde of the finish on the treated fabric were examined by SEM,gas chromatography and other methods.The results indicated that the photocatalytic efficiency of the cotton fabric with Pd modified TiO2was increased by 49% as compared with the cotton fabric without Pd modified TiO2,and it also had a very good UV protective effect.HAP faciliated the adhesion of photocatalytic agent on the surface of cotton fabric.
出处 《纺织学报》 EI CAS CSCD 北大核心 2009年第2期79-83,共5页 Journal of Textile Research
基金 浙江省自然科学基金资助项目(Y406310)
关键词 光催化 TIO2 改性 HAP整理 PD photocatalysis TiO2 modifying HAP treatment palladium
  • 相关文献

参考文献6

  • 1HOFFMANN M R, MARTIN S T, CHOI W, et al. Applications of semiconductor photocatalysis [ J ]. Chem Rev, 1995,95(1):69.
  • 2SUBRAMANIAN V, WOLF E, KAMAT P V. Semiconductor-metal composite nanostructures : to what extent do metal nanoparticles improve the photocatalytic activity of TiO2 films[J]. J Phys Chem B, 2001,105(46): 11439.
  • 3黄龙全,徐英莲,傅雅琴.纳米羟基磷灰石对光催化棉织物的保护性能[J].纺织学报,2008,29(2):60-63. 被引量:5
  • 4张兴旺,周明华,徐甦,雷乐成.载银TiO_2/沸石催化剂的制备、表征以及光催化性能的研究[J].浙江大学学报(工学版),2005,39(10):1623-1626. 被引量:8
  • 5TURCHI C S, OLLIS D F. Photocatalytic degradation of organic water contaminants mechanisms involving hydroxyl radical attack [J]. Journal of Catalysis, 1990, 122:178 - 189.
  • 6SCLAFANI A, HERRMANN J M. Influence of metallic silver and of platinum-silver bimetallic deposits on the photocatalytic activity of titania (anatase and ruffle ) in organic and aqueous media [J]. J Photochem Photobiol A, 1998,113(2) : 181.

二级参考文献14

  • 1刘今强,邵建中,张玲玲,周岚,俞思琴.纳米材料在棉制品上的固着技术[J].纺织学报,2006,27(9):5-8. 被引量:7
  • 2ARABATZIS I M, STERGIOPOULOS T, BERNARD M C. Silver-modified titanium dioxide thin films for efficient photodegradation of methyl orange [J]. Appl Catal B: Environ, 2003,42 (1): 187-201.
  • 3ZHOU Y, WANG C Y, LIU H J, et al. Preparation and studies of Ag-TiO2 hybrid nanoparticles of core-shell structure [J]. Mater Sci Eng: B, 1999, 67 (1): 95-98.
  • 4SANIO T, NEGISHI N, MAS D, et al. Photocatalytic Decomposition of N2O on Highly Dispersed Ag+ Ions on TiO2 Prepared by Photodeposition [J]. J Catal, 2000,194 (1): 71-79.
  • 5LEI L C, CHU H, HU X, et al. Preparation of heterogeneous photocatalyst (TiO2/Alumina) by MOCVD [J]. Ind Eng Chem Res, 1999,38 (2): 3381-3385.
  • 6VERONICA V, ROSE A, DONIA B. Photocatalytic oxidation of organics in water using pure and silver-modified titanium dioxide particle [J]. J Photochem Photobiol A: Chem, 2002,148 (2): 233-245.
  • 7SERPONE N. Relative photonic efficiencies and quantum yields in heterogeneous photocatalysis [J]. J Photochem Photobiol A: Chem, 1997,104 (1): 1-12.
  • 8FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode [J]. Nature, 1972, 37(1): 238-245
  • 9SOPYAN I, WATANABE M, MURASAWA S, et al. An efficient TiO2 thin-film photocatalyst: photocatalytic properties in gas-phase acetaldehyde degradation [J]. J Photochem Photobiol A: Chem, 1996, 98 (1): 79-86.
  • 10姚穆,周锦芳,黄淑珍,等.纺织材料学[M].2版.北京:中国纺织出版社,2000:250.

共引文献11

同被引文献85

引证文献5

二级引证文献9

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部