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两种含二苯膦基二茂铁酮亚胺席夫碱的合成与表征 被引量：1

Synthesis and characterization of two novel ferrocenylimino Schiff-bases containing diphenylphosphinyl groups
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摘要 以二茂铁、醋酸酐和苯甲酰氯为原料,经过傅克反应和酮胺缩合等反应,合成了标题化合物。讨论了催化剂、溶剂、反应时间和投料计量比对目标产物收率的影响。通过红外光谱、核磁共振氢谱与碳谱、质谱及元素分析对产物的结构进行了表征,并研究了其电化学性质。 Two ferrocenylimino Schiff-bases [（η^5C5H5）Fe{（η^5C5H4）—C（CH3）N—（C6H4-o-PPh2）}] and [（η^5C5H5）Fe{（η^5C5H4）—C（C6H5）N—（C6H4-o-PPh2）}] were synthesized from ferrocene,acetic anhydride and benzoyl chloride used as raw materials through the Friedel-Crafts and ketoamine condensation reactions.The effects of catalysts,solvents,molar ratio of reactants and reaction time on product yield were investigated.The two compounds were characterized by IR,and 1HNMR,13CNMR,and elemental analysis,and their electrochemical properties were also studied.
作者 黄昕 匡仁云 曹迁永 林森 邓晓玲
机构地区 南昌大学化学系 井冈山大学化学化工学院 南昌大学档案馆
出处 《化学试剂》 CAS CSCD 北大核心 2009年第3期173-176,共4页 Chemical Reagents
基金 江西省教育厅(赣教技字[2006]29号) 南昌大学创新团队资金项目
关键词 二茂铁 席夫碱 酮胺缩合反应 合成与表征 ferrocene Schiff-bases ketoamine condensation reaction synthesis and characterization
分类号 O625.632 [理学—有机化学]
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参考文献11

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二级参考文献2

共引文献9

同被引文献13

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化学试剂
2009年 第3期

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