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Electrochemical noise characteristics in corrosion process of AZ91D magnesium alloy in neutral chloride solution 被引量:7

Electrochemical noise characteristics in corrosion process of AZ91D magnesium alloy in neutral chloride solution
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摘要 The corrosion process of AZ91D magnesium alloy in neutral 1%(mass fraction) sodium chloride aqueous solution was investigated by electrochemical noise(EN),SEM and EDX. Fractal theory was primarily used to depict the corrosion process of the alloy. The fast wavelet transform(FWT),as well as the fast Fourier transform(FFT),was employed to analyze the EN data. The results show that the overall corrosion process can be described by three stages. The first stage corresponds to the pit nucleation and growth; the second stage involves the growth of a passive oxide layer; and the third stage involves reactivation. With increasing immersion time,fractal dimension increases fast initially,fluctuates in the medium and increases again at last. Pitting corrosion and fractal dimension increase due to the initiation and formation of pits in the initial and the end of immersion,while depresses due to the passivation in the medium period. The results of SEM and EDX support the above conclusions. The corrosion process of AZ91D magnesium alloy in neutral 1% (mass fraction) sodium chloride aqueous solution was investigated by electrochemical noise(EN), SEM and EDX. Fractal theory was primarily used to depict the corrosion process of the alloy. The fast wavelet transform(FWT), as well as the fast Fourier transform(FFT), was employed to analyze the EN data. The results show that the overall corrosion process can be described by three stages. The first stage corresponds to the pit nucleation and growth; the second stage involves the growth of a passive oxide layer; and the third stage involves reactivation. With increasing immersion time, fractal dimension increases fast initially, fluctuates in the medium and increases again at last. Pitting corrosion and fractal dimension increase due to the initiation and formation of pits in the initial and the end of immersion, while depresses due to the passivation in the medium period. The results of SEM and EDX support the above conclusions.
出处 《中国有色金属学会会刊:英文版》 SCIE EI CAS CSCD 2009年第2期496-503,共8页 Transactions of Nonferrous Metals Society of China
基金 Projects(50471043, 50771092) supported by the National Natural Science Foundation of China Project(2005DKA10400-Z15) supported by the National R&D Infrastructure and Facility Development Program of China Project supported by Key Laboratory for Ultra-light Materials and Surface-treatment Technology of Education Ministry of China
关键词 AZ91D镁合金 电化学噪音 腐蚀过程 中性溶液 噪声特性 快速傅立叶变换 氯化钠水溶液 快速小波变换 AZ91D magnesium corrosion electrochemical noise fractal dimension
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