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Synthesis and mass spectral fragmentations of new spiro heterocycles

Synthesis and mass spectral fragmentations of new spiro heterocycles
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摘要 The reaction of dichlorodiphenoxymethane (2) with ortho-functionlized benzoic acids 1a–c yielded the spiro derivatives of bezodioxinone 4a, benzoxazinone 4b and benzodioxepinone 4c. The same reaction with 1,8-diaminonaphthalene afforded the spiro perimidine 6, while with 1,1′-binaphthyl-2,2′-diol gave the semi-cyclized derivative 2,2-diphenoxydinaphthodioxepine 8. The reaction of dichlorodiphenoxymethane (2) with ortho-functionlized benzoic acids 1a–c yielded the spiro derivatives of bezodioxinone 4a, benzoxazinone 4b and benzodioxepinone 4c. The same reaction with 1,8-diaminonaphthalene afforded the spiro perimidine 6, while with 1,1′-binaphthyl-2,2′-diol gave the semi-cyclized derivative 2,2-diphenoxydinaphthodioxepine 8.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第6期689-693,共5页 中国化学快报(英文版)
关键词 Spiroorthocarbonate Azaspiro compounds Oxaazaspiro compounds Spiroorthocarbonate Azaspiro compounds Oxaazaspiro compounds
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