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Experimental and mechanism studies on simultaneous desulfurization and denitrification from flue gas using a flue gas circulating fluidized bed 被引量:11

Experimental and mechanism studies on simultaneous desulfurization and denitrification from flue gas using a flue gas circulating fluidized bed
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摘要 The oxidizing highly reactive absorbent was prepared from fly ash,industry lime,and an oxidizing additive M.Experiments of simultaneous desulfurization and denitrification were carried out in a flue gas circulating fluidized bed(CFB).The effects of influencing factors and calcium availability were also investigated on the removal efficiencies of desulfurization and denitrification.Removal efficiencies of 95.5%for SO2 and 64.8%for NO were obtained respectively under the optimal experimental conditions. The component of the spent absorbent was analyzed with chemical analysis methods.The results in- dicated that more nitrogen species appeared in the spent absorbent except sulfur species.A scanning electron microscope(SEM)and an accessory X-ray energy spectrometer were used to observe micro-properties of the samples,including fly ash,oxidizing highly reactive absorbent and spent absorbent.The simultaneous removal mechanism of SO2 and NO based on this absorbent was pro- posed according to the experimental results. The oxidizing highly reactive absorbent was prepared from fly ash, industry lime, and an oxidizing additive M. Experiments of simultaneous desulfurization and denitrification were carried out in a flue gas circulating fluidized bed (CFB). The effects of influencing factors and calcium availability were also investigated on the removal efficiencies of desulfurization and denitrification. Removal efficiencies of 95.5% for SO2 and 64.8% for NO were obtained respectively under the optimal experimental conditions. The component of the spent absorbent was analyzed with chemical analysis methods. The results indicated that more nitrogen species appeared in the spent absorbent except sulfur species. A scanning electron microscope (SEM) and an accessory X-ray energy spectrometer were used to observe micro-properties of the samples, including fly ash, oxidizing highly reactive absorbent and spent absorbent. The simultaneous removal mechanism of SO2 and NO based on this absorbent was proposed according to the experimental results.
出处 《Science China Chemistry》 SCIE EI CAS 2007年第1期135-144,共10页 中国科学(化学英文版)
基金 the Significant Pre-research Foundation of North China Electric PowerUniversity(D03-035)
关键词 FLUE gas circulating fluidized bed simultaneous DESULFURIZATION and DENITRIFICATION OXIDIZING highly reactive ABSORBENT MECHANISM flue gas circulating fluidized bed simultaneous desulfurization and denitrification oxidizing highly reactive absorbent mechanism
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