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Asymmetrical Conductivity of TCNQ Modificd Au/Thiol-Lipid Bilayers in Fe(CN)_6^(3-/4-)solution

Asymmetrical Conductivity of TCNQ Modificd Au/Thiol-Lipid Bilayers in Fe(CN)_6^(3-/4-)solution
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摘要 In this work. elcctron transfer across Au supported octadecanethiolphosphatidyl choline (Au/ODT-PC) bilayers, which were modified with 7.7.8.8-tetracyanoquinodimethane (TCNQ). were investigated using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). Results of EIS experiments show that the TCNQ molecules act as electron conductors in the bilayer. Cyclic voltammetry indicates that the TCNQ modified Au/thiol-lipid bilayers display strong asymmetrical conductivity in Fe(CN)3-/4-6 solution. In this work. elcctron transfer across Au supported octadecanethiolphosphatidyl choline (Au/ODT-PC) bilayers, which were modified with 7.7.8.8-tetracyanoquinodimethane (TCNQ). were investigated using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). Results of EIS experiments show that the TCNQ molecules act as electron conductors in the bilayer. Cyclic voltammetry indicates that the TCNQ modified Au/thiol-lipid bilayers display strong asymmetrical conductivity in Fe(CN)3-/4-6 solution.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第7期587-590,共4页 中国化学快报(英文版)
关键词 ELECTROCHEMISTRY supported bilayer electrochemical impedance spectroscopy cyclic voltammetry asymmetrical conductivity Electrochemistry,supported bilayer,electrochemical impedance spectroscopy,cyclic voltammetry,asymmetrical conductivity
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