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2-(2,4-二氟苯基)-5-烷氧甲基吡啶的合成 被引量：1

Synthesis of 2-(2,4-Difluoro)Phenyl-5-Alkyloxy Methyl Pyridine Derivatives
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摘要 以2,5-二溴吡啶和溴代烷为原料,通过甲酰化、还原、成醚和Suzuki-Miyaura交叉偶联等反应,合成得到了2-(2,4-二氟苯基)-5-烷氧甲基吡啶衍生物,探讨了分子结构对成醚和Suzuki-Miyaura交叉偶联反应的影响,甲酰化、还原、成醚和Suzuki-Miyaura交叉偶联等反应的产率分别达到了49.8%、96.0%、90.3%和96.9%. A class of 2-（2,4-difluoro）phenyl-5-alkyloxy methyl pyridine derivatives was synthesized by formylation reaction, reduction reaction, ether-forming reaction and Suzuki-Miyaura eorss-coupling reaction, respectively. The influence of molecular structure on the ether-forming reaction and Suzuki-Miyaura corss-coupling reaction was also investigated. The yileds of formylation reaction, reduction reaction, etherforming reaction and Suzuki-Miyaura eorss-coupling reaction were 49.8 %, 96.0 %, 90. 3 % and 96.9 %, respectively.
作者 朱卫国 朱克明 梁爱辉 罗剑 刘煜 马小云 朱美香
机构地区 湘潭大学化学学院环境友好化学与应用教育部重点实验室
出处 《湘潭大学自然科学学报》 CAS CSCD 北大核心 2009年第1期53-58,共6页 Natural Science Journal of Xiangtan University
基金 国家自然科学基金资助项目(20772010 50473046) 湖南省科技厅资助项目(2007FJ3017) 湖南省自然科学基金资助项目(06JJ20008)
关键词 2-(2 4-二氟苯基)-5-烷氧甲基吡啶 6-溴-3-吡啶甲醇 合成 2- （2,4-difluoro） phenyl-5-alkyloxy methyl pyridine 6-bromo-3-pyridinyl methanol synthesis
分类号 O614.1 [理学—无机化学]
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参考文献23

  • 1BALDO M A, LAMANSKY S, BURROWS P E, et al. Very high-efficiency green organic light- emitting devices based on electrophosphorescence [J]. Appl Phys Lett, 1999, 75:4-6.
  • 2ADACHI C, BALDO M A, FORREST S R, et al. High-efficiency red electrophosphorescence devices [J]. Appl Phys Lett, 2001, 78:1 622-1 624.
  • 3IKAI M, TOKITO S, SAKAMOTO Y T, et al. Highly efficient phosphorescence from organic light-emitting devices with an excit-on-block layer [J]. Appl Phys Lett, 2001, 79: 156-158.
  • 4LASKAR I R, CHEN T M. Tuning of wavelength: synthesis and photophysical studies of iridium complexes and their applications in organic light emitting devices [J]. Chem Mater, 2004, 16: 111-117.
  • 5TSUZUKI T, SHIRASAWA N, SUZUKI T, et al. Color tunable organic light emitting diodes using pentafluoro -ogenyl-substituted iridium complexes[J].Adv Mater, 2003, 15:1 455-1 458.
  • 6TAMAYO A B, ALLAYNE B D, DJUROVICH P I, et al. Synthesis and characterization of facial and meridional tris-cyclometalated iridium(Ⅲ) complexes [J]. J Am Chem Soc, 2003, 125:7 377-7 387.
  • 7HOLMES R J, ANDRADE W D, FORREST S R, et al. Efficient, deep-blue organic electrophos phorescence by guest charge trapping[J]. Appl Phys Lett, 2003, 83:3 818-3 820.
  • 8TOKITO S, LIJIMA T, SUZURI Y, et al. Confinement of triplet energy on phosphorescent molecules for highly-efficient organic blue-light-emitting devices [J]. Appl Phys Lett, 2003, 83:569 571-569 573.
  • 9DEDEIAN K, SHI J, SHEPHERD N,et al. Photophysieal and electrochemical properties of heteroleptic tris-cyclometalated iridium (Ⅲ) complexes[J]. Inorg Chem, 2005, 44: 4 445-4 447.
  • 10SAJOTO T, THOMPSON M E, FORREST R, et al. Blue and near-UV phosphorescence from iridium complexes with cyclometalated pyrazolyl or N-heterocyclic carbene ligands [J]. Inorg Chem, 2005, 44:7 992-8 003.

同被引文献27

  • 1Su, S. J.; Sasabe, H.; Takeda, T.; Kido, J. Chem. Mater. 2008, 20, 1691.
  • 2Xiao, L.; Su, S. J.; Agata, Y.; Lan, H.; Kido, J. Adv. Mater. 2009, 21, 1271.
  • 3Hsu, F.-M.; Chien, C.-H.; Shu, C.-F.; Lai, C.-H.; Hsieh, C.-C.; Wang, K.-W.; Chou, P.-T. Adv. Funct. Mater. 2009, 19, 2834.
  • 4Su, S. J.; Takahashi, Y.; Chiba, T.; Takeda, T.; Kido, J. Adv. Funct. Mater. 2009, 19, 1260.
  • 5Li, X. H.; Cao, Y.; Huang, C. H. Inorg. Chem. 2007, 46, 5518.
  • 6Lo, S. C.; Richards, G. J.; Markham, P. J.; Namdas, E. B.; Sharma, S.; Burn, P. L.; Samuel, I. D. W. Adv. Funct. Mater. 2005, 15, 1451.
  • 7Lo, S. C.; Harding, R. E.; Shipley, C. P.; Stevenson, S. G.; Burn, P. L.; Samuel, I. D. W. J. Am. Chem. Soc. 2009, 131, 16681.
  • 8Kwon, T.-H.; Kim, M.-K.; Kwon, J.; Shin, D.-Y.; Park, S.-J.; Lee, C.-L.; Kim, J.-J.; Hong, J.-1. Chem. Mater. 2007, 19, 3673.
  • 9Wen, Z. L.; Hu, Z. Y.; Liu, Y.; Xiao, F. L.; Ma, X. Y.; Zhu, M. X.; Zhu, W. G. J. Cent. South Univ. Technol. 2009, 16, 0380.
  • 10Lia, B. L.; Liua, Z. T.; Hea, Y. M.; Pana, J.; Fan, Q. H. Polymer 2008, 49, 1527.

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湘潭大学自然科学学报
2009年 第1期

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