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小麦秸秆的γ辐照与NaOH溶液的协同预处理 被引量:7

Pretreatment of Wheat Straw by γ-ray Radiation and Alkali Solution
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摘要 通过考察辐照剂量、辐照与NaOH溶液浸泡组合顺序、NaOH溶液浓度、NaOH溶液浸泡时间等因素,研究了较低剂量辐照与NaOH溶液温和浸泡协同预处理工艺。对还原糖得率、组分改变、结晶度等进行了分析,对该协同工艺的作用机理进行了探讨。实验结果表明,单纯的较低剂量辐照对麦秸的组分及结晶度的改变作用不明显,但可大幅降低后续碱浸泡所需的用量和时间。经组合工艺处理后,麦秸的相关特征参数均发生了明显改变。较适宜的组合预处理工艺为小麦秸秆经100 kGy辐照,然后以2%NaOH溶液浸泡1 h,其酶解还原糖得率达到理论产率的78.2%。 Gamma ray radiation and alkali solution pretreatment of wheat straw and its effect on enzymatic hydrolysis were studied. The result shows that the γ-irradiation can significantly decrease the initial concentration of alkali solution and shorten the pretrea- ted time, but the changes in the physical and chemical properties of only irradiated wheat straw are indistinctive. A synergistic effect between irradiation and alkali solution pretreatment was observed. Reducing sugar yield is 78.2% (accounted for theoretical yield) after wheat straw is radiated at a dose of 100 kGy and then with 2%NaOH pretreated forl h.
出处 《原子能科学技术》 EI CAS CSCD 北大核心 2009年第4期304-310,共7页 Atomic Energy Science and Technology
基金 国家自然科学基金资助项目(50678089)
关键词 小麦秸秆 Γ辐照 NAOH溶液 预处理 酶水解 wheat straw gamma ray radiation NaOH solution pretreatment enzyme hydrolysis
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参考文献21

  • 1杨春平,沈志强,喻国策,王建龙.γ射线辐照预处理对麦秸纤维素酶水解产糖的影响[J].原子能科学技术,2009,43(1):36-40. 被引量:8
  • 2HON D N S. Formation and behavior of mechanoradicals in pulp cellulose [J]. Journal of Applied Polymer Science, 1979, 23:1 487-1 499.
  • 3KHAN F. Characterization of methyl methacrylate grafting onto preirradiated biodegradable lignocellulose fiber by γ-radiation[J]. Macromol Biosci, 2005, 5:78-89.
  • 4KUMAKURA M, KAETSU I. Radiation- induced degradation and subsequent hydrolysis of waste cellulose materials[J]. International Journal of Applied Radiation and Isotopes, 1979, 30(3):139-141.
  • 5LU Z, KUMAKURA M. Effect of radiation pre-treatment on enzymatic hydrolysis of rice straw with low concentrations of alkali solution[J]. Bioresource Technol, 1993, 43: 13-17.
  • 6CHOSDU R, HILMY N, ERLINDA E T B, et al. Radiation and chemical pretreatment of cellulosic waste[J]. Radiat Phys Chem, 1993, 42(4- 6) : 695-698.
  • 7BANCHORNDHEVAKUL S. Effect of urea and urea-gamma treatments on cellulose degradation of Thai rice straw and corn stalk[J]. Radiat Phys Chem, 2002, 64(5-6):417-422.
  • 8AL-MASRI M R, GUENTHER K D. Changes in digestibility and cell-wall constituents of some agricultural by-products due to gamma irradiation and urea treatments[J].Radiat Phys Chem, 1999, 55(3) : 323-329.
  • 9KUMAKURA M, KAETSU I. Heat enhancement effects in radiation pretreatment of cellulosic wastes[J]. Industrial & Engineering Chemistry Research: Product Research and Development, 1984, 23(1): 88-91.
  • 10张琳,顾汉泉,高仁孝.辐射对纤维素结晶度的影响[J].火炸药学报,2002,25(1):76-77. 被引量:11

二级参考文献15

  • 1许洪林,张文辉.^(60)COγ辐射引发的木材自由基[J].辐射研究与辐射工艺学报,1994,12(4):214-219. 被引量:5
  • 2李宝忠,张利华,于家艳.辐照聚酰胺1010的后效应[J].辐射研究与辐射工艺学报,1996,14(3):153-156. 被引量:5
  • 3KHAN F, AHMAD S R, KRONFLI E. γ-radiation induced changes in the physical and chemical properties of lignocellulose [J]. Biomacromolecules, 2006, 7:2 303-2 309.
  • 4CHARLESBY A. Crosslinking and degradation of polymers[J]. Radiat Phys Chem, 1981, 18: 59-66.
  • 5GLEGG R E, KERTESZ Z I. Aftereffect in the degradation of cellulose and pectin by gamma rays[J]. Science, 1956, 124(3 227): 893-894.
  • 6KUMAKURA M, KAETSU I. Heat enhancement effects in radiation pretreatment of cellulosic wastes[J]. Industrial & Engineering Chemistry, Product Research and Development, 1984, 23(1) : 88-91.
  • 7LU Zhaoxin, KUMAKURA M. Effect of radiation pretreatment on enzymatic hydrolysis of rice straw with low concentrations of alkali solution [J]. Bioresource Technol, 1993, 43(1):13-17.
  • 8何源禄 王玉华.苏联植物纤维原料辐射水解研究进展.核技术,1987,2:1-6.
  • 9宁正祥.食品成分分析手册[M].北京:中国轻工业出版社,2001..
  • 10O'CONNOR R T,et al. Infrared spectrophotometic Proceduce for analysis of cellulose and modified collulose [J]. Anal Chem, 1957,29:998.

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