摘要
Two novel cobalt(Ⅱ) compounds were obtained and characterized by X-ray sing- le-crystal diffraction, IR, 1H NMR and elemental analysis. Compound 1 crystallizes in monoclinic, space group P21/n, with a = 18.046(4), b = 11.335(3), c = 19.157(5)A, β = 92.707(3)°, Z = 4, V = 3914.4(16) A3, Mr = 968.56, Dc = 1.644 g/cm3, μ = 1.378 mm^-1, F(000) = 1960, the final R = 0.0367 and wR = 0.0895. The crystal of compound 2 is of monoclinic, space group P211c with a = 8.7253(10), b = 10.9031(13), c = 18.235(2)A,β = 93.2210(10)°, Z = 4, V = 1732.0(3)A3, Mr = 464.21, Dc = 1.780 g/cm3,μ = 1.560 mm-1, F(000) = 932, the final R = 0.0322 and wR = 0.0743.
Two novel cobalt(Ⅱ) compounds were obtained and characterized by X-ray sing- le-crystal diffraction, IR, 1H NMR and elemental analysis. Compound 1 crystallizes in monoclinic, space group P21/n, with a = 18.046(4), b = 11.335(3), c = 19.157(5)A, β = 92.707(3)°, Z = 4, V = 3914.4(16) A3, Mr = 968.56, Dc = 1.644 g/cm3, μ = 1.378 mm^-1, F(000) = 1960, the final R = 0.0367 and wR = 0.0895. The crystal of compound 2 is of monoclinic, space group P211c with a = 8.7253(10), b = 10.9031(13), c = 18.235(2)A,β = 93.2210(10)°, Z = 4, V = 1732.0(3)A3, Mr = 464.21, Dc = 1.780 g/cm3,μ = 1.560 mm-1, F(000) = 932, the final R = 0.0322 and wR = 0.0743.