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新型杀虫剂烯啶虫胺 被引量:19

The Novel Insecticide of Nitenpyram
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摘要 烯啶虫胺(试验代号:TI-304;通用名称:Nitenpyram;商品名称:Besguard)是由日本武田公司于1989年开发的烟酰亚胺类杀虫剂,并于1995年在日本获得登记。 Novel neonicotinoid insecticide nitenpyram was briefly introduced,including its structure, physical and chemical properties and mechanism of action etc.It was emphasized on the methods for synthesis of nitenpyram and its intermediates.Starting with 2-chloro-5-chloromethylpyridine, the major intermediate N-(6-chloro-3-pyridyl) methyl-N-ethylamine was synthesized,then which reacted with 1,1-dimethyl mercapto-2-nitroethylene or 1,1,1-trichloro -2-nitroethane,the acquired intermediate reacted with aqueous methylamine,thus the objective product nitenpyram was obtained.The produced domestically nitenpyram can't meet market demand at present yet,so nitenpyram still had wide application and market prospect
作者 孙慧 杨春河
出处 《精细与专用化学品》 CAS 2009年第11期16-18,共3页 Fine and Specialty Chemicals
关键词 新型杀虫剂 烯啶虫胺 通用名称 商品名称 日本 胺类 insecticide nitenpyram 2-chloro-5-chloromethylpyridine methylamine
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