摘要
在反应气体参与的催化反应中,超临界CO2作为溶剂的主要优势是消除气体的溶解性能差所带来的传质问题,同时提高实验室和化工生产中的安全系数。介绍了超临界CO2介质中气体参与的催化反应的特点以及在催化加氢、羰基化和催化氧化等反应中的研究进展,并对未来的发展提出展望。
Supercritical CO2 can eliminate mass transport limitations in catalytic reaction with gases reactants and makes the scCO2 very attractive for improve the safety in laboratory and chemical industrial production. In this work, taking the reactions of hydrogenation, hydroformylation and oxidation as examples, recent research progress about catalytic reaction on the use of gaseous reactants with supercritical CO2 as reaction media were reviewed. Finally, the developing trends are discussed.
出处
《河北化工》
2009年第6期5-7,共3页
Hebei Chemical Industry
基金
国家自然科学基金(20506011)
国家"973项目"(2006CB705809)
关键词
超临界CO2
催化反应
催化加氢
羰基化反应
催化氧化
supercritical carbon dioxide
catalytic reaction
hydrogenation
hydroformylation
oxidation
