摘要
本文介绍以超临界ＣＯ２流体为介质的高分子合成的研究进展。说明可在超临界二氧化碳中实施氟代单体的自由基溶液聚合、甲基丙烯酸甲酯和苯乙烯的分散聚合、丙烯酸的沉淀聚合、丙烯酰胺的反相乳液聚合以及异丁基乙烯基醚的阳离子聚合等多种聚合反应。这显示出超临界ＣＯ２是一种对环境无污染且价廉的替代溶剂。
This review summarizes the polymer preparation that has been carried out in supercritical carbon dioxide.A number of polymerization reactions,such as the homogeneous free radical polymerization of flourinated monomers,the dispersion polymerization of methyl methacrylate and styrene,the precipitation polymerization of acrylic acid,the inverse emulsion polymerization of acrylamide and the cationic polymerization of isobutyl vinyl ether,can be conducted in supercritical carbon dioxide.This indicates that a wide range of polymers can be prepared in this environmentally sound and inexpensive supercritical carbon dioxide.
出处
《化学进展》
SCIE
CAS
CSCD
1998年第2期202-206,共5页
Progress in Chemistry
基金
国家自然科学基金
浙江省自然科学基金
关键词
超临界二氧化碳
自由基聚合
阳离子聚合
supercritical carbon dioxide
free radical polymerization
cationic polymerization
