摘要
由于对日趋严重的温室效应的担忧,对廉价二氧化碳的固定和转化成为一个非常有吸引力的研究领域。本文主要介绍了二氧化碳参与的有机化学反应,包括与环氧化合物、胺类化合物、不饱和碳氢化合物以及醇类和烃类等化合物的反应。文章分别对这几类反应的发展历程、研究现状进行了总结,重点介绍了各反应所用到的催化剂体系及有关反应机理,并展望了该领域的研究前景。
Chemical fixation of carbon dioxide is a very attractive subject not only from viewpoint of carbon resource utilization, but also from increasing environmental concerns. The latest progress in the research of organic reactions utilizing carbon dioxide is reviewed, particularly including the reactions with epoxides, amines, unsaturated compounds, alcohols, hydrocarbons, etc. This review summarizes the organic reactions with carbon dioxide including catalyst design and corresponding reaction mechanism. The outlook of the research area is also provided.
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2009年第6期1217-1228,共12页
Progress in Chemistry
基金
上海市"浦江计划"基金项目(No.07pz14033)资助
关键词
二氧化碳
反应
催化
carbon dioxide
reactions
catalysis
