摘要
采用溶剂热方法,以苯乙烯为还原剂和配位剂,合成了宽度为40nm-60nm、长度为600nm-1μm铋纳米带,并对其反应机理进行了探讨。在铋纳米带的合成中,α-铋的层状结构是形成铋纳米带的关键因素。配位试剂在各晶面的吸附对产物的形貌具有重要影响。通过改变配位试剂与铋盐的质量比,可以实现对铋纳米结构和形貌的调控。
In solvothermal conditions, styrene was taken to be reductant and complexant and bismuth nanobelts were synthesized. The width and the length of bismuth nanobelts are 40 nm-60 nm and 600 nm-1 μm respectively, the mechanism of the formation of bismuth nanobelts were discussed. The laminar structure of the -bismuth is the key factor for production of bismuth nanobehs. The morphology of bismuth nanostructures can be controlled by tuning up the molar ratio of complexant to Bi.
基金
国家863计划资助项目（编号：2004AA001520）
关键词
金属材料
纳米带
苯乙烯
溶剂热合成
metallic materials
nanobehs
styrene
solvothermal synthesis
