期刊文献+

镍配合物[Ni(C_(10)H_8N_2)(C_7H_4O_5N_3)(H_2O)]·ClO_4的合成及晶体结构 被引量:2

Synthesis and crystal structure of [Ni(C_(10)H_8N_2)(C_7H_4O_5N_3)(H_2O)]·ClO_4
下载PDF
导出
摘要 The title complex[Ni(C10H8N2)(C7H4O5N3)(H2O)]ClO4 was synthesized by Taurine 2-hydroxy-3,5-dinitrobenzaldehyde schiff base,2,2’-bipyridine and nickel(II) perchloride in ethanol solution,and the crystal structure was determined by X-ray diffraction method.The crystal belongs to Monoclinic system,space group P21/c,with cell parameters:a=7.4481(3),b=24.1832(9),c=11.6691(4),β=98.021(2)°,V=2081.26(13)3.The nickel(II) atom is coordinated by two N atoms from one 2,2’-bipyridine molecule,one O atom and one N atom from a 2-hydroxy-3,5-dinitrobenzaldehyde imine molecule,one O atom from a coordinated water,resulting in a square-pyramid geometry.The packing diagram shows that a three-dimensional network is formed via intermolecular attractive force. The rifle complex [ Ni ( C10 H8 N2 ) ( C7 H4 O5 N3 ) ( H2O ) ] AClO4 was synthesized by Taurine 2-hydroxy-3, 5- dinitrobenzaldehyde schiff base , 2,2'-bipyridine and nickel (Ⅱ) perchloride in ethanol solution, and the crystal structure was determined by X-ray diffraction method. The crystal belongs to Moneclinic system, space group P21/c, with cell parameters:a = 7. 4481(3) ,b =24. 1832(9) ,c = 11.6691(4)A,β=98.021(2)°,V=2081.26(13)A^3.The nickel (II) atom is coordinated by two N atoms from one 2,2' -bipyridine molecule,one O atom and one N atom from a 2-hydroxy-3,5-dinitrobenzaldehyde imine molecule , one O atom from a coordinated water,resulting in a square-pyramid geometry. The packing diagram shows that a three-dimensional network is formed via intermolecular attractive force.
机构地区 井冈山大学
出处 《化学研究与应用》 CAS CSCD 北大核心 2009年第8期1124-1128,共5页 Chemical Research and Application
基金 江西省教育厅科技项目资助(GJJ09332)
关键词 合成 晶体结构 镍配合物 synthesis crystal structure nickel complex
  • 相关文献

参考文献10

二级参考文献95

  • 1胡扬剑,江洪流,王海华.苊二亚胺氯化镍配合物/烷基铝催化乙烯聚合的研究[J].石油化工,2004,33(10):937-940. 被引量:2
  • 2石进超,郑晓晖,阿米娜.14种二茂铁亚胺类化合物的制备和紫外-可见光谱研究[J].西北大学学报(自然科学版),1995,25(1):15-17. 被引量:1
  • 3Yokel R A, Allen D D, Burgi D E, et al. J Pharmacol. Toxicol. Meth. , 1992, 27: 135.
  • 4Zuleta J A, Bevilacqua J M, Proserpio D M, et al. Inorg. Chem. , 1992, 31: 2396.
  • 5PAN Qing-cai,PENG Zheng—he,Ni Xiao-ling,et al(潘庆才,彭正合,倪筱玲等).Spectroscopy and Spectral Analysis(光谱学与光谱分析),1998,18(4):11.
  • 6PENG Zheng-he, PAN Qing-cai, REN Xiao-ming, et al (彭正合,潘庆才,任小明等). Chinese J. of Inorganic Chem. (无机化学学报),1997, 13(3): 351.
  • 7PAN Qing-eai, PENG Zheng-he, QIN Zi-bin (潘庆才,彭正合,秦子斌). Chemical Researches (化学研究), 1998, 9(2) : 31.
  • 8PAN Qing-cai, PENG Zheng-he, QIN Zi-bin, et al (潘庆才,彭正合,秦子斌等). Teachers University Journal of Yantai (烟台师范学院学报), 2000, 16(2): 120.
  • 9Hodnett, E. M.; Dunn, W. J.J. Med. Chem. 1972, 15, 339.
  • 10Jabri, E.; Carr, M. B.; Hausinger, R. P.; Karplus, P. A. Science 1995, 268, 998-1003.

共引文献49

同被引文献33

引证文献2

二级引证文献3

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部