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三氯化磷生产工艺的优化 被引量:6

Optimization of phosphorus trichloride production process
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摘要 对三氯化磷生产工艺进行了改进:在不停车的情况下,依据黄磷与氯气反应和黄磷与五氯化磷反应时温度与压力的不同变化判断氯化釜内的底磷量;液氯汽化设备由用热水加热的汽化罐改为用蒸汽加热的套管式汽化器;精馏塔中的列管式换热器改为布液器,夹套式冷却器改为喷淋式冷凝器;压磷泵投磷改为水压式投磷等。进行这些工艺优化后,三氯化磷的生产能力由250 t/月提高到350 t/月以上,产品质量等级由合格品提升到优等品,设备的使用寿命延长,液氯汽化速度加快,换热效率提高,消除了三氯化氮富集爆炸的隐患,提高了生产系统的安全系数,改善了生产环境,节约了动力电和维修费。 The production process of phosphorus trichloride was optimized as fellows: the amount of residual phosphorus in the chlorination reactor was judged without shutdown by the different change of the temperature and pressure of the reaction of yellow phosphorus with chlorine gas and the reaction of yellow phosphorus with phosphorus pentachloride; A double-pipe vaporizer heated by steam substituted for the vaporizing tank heated by hot water to vaporize liquid chlorine; the tubular heat exchanger in the distillation column was transformed into a liquid distributor, and the jacket cooler was transformed into a spray condenser; and pumping phosphorus was replaced by hydraulic charging. After the above improvements were carried out, the following effects were obtained : the production capacity of phosphorus trichloride was increased from 250 tons to above 350 tons monthly; the quality of products improved from qualified grade to top grade; the service life of equipment was prolonged; the rate of liquid chlorine vaporization was speeded up; the efficiency of heat exchange was increased; the hidden danger of nitrogen trichloride explosion was eliminated; the safety factor of the production system was increased; the production surroundings were improved; and the costs of power and maintenance were saved.
作者 王志勇
出处 《氯碱工业》 CAS 2009年第8期27-32,共6页 Chlor-Alkali Industry
关键词 三氯化磷 生产工艺 液氯汽化 精馏塔 黄磷 氯气 phosphorus trichloride production process liquid chlorine vaporization distillation column yellow phosphorus chlorine gas
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