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ZSM-5分子筛填充硅橡胶膜在乙醇/水体系中的溶胀特性 被引量:4

Swelling characteristics of zeolite filled polydimethysiloxane membrane dipped in ethanol-water solution
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摘要 采用液相共混的方法制备了ZSM-5分子筛填充硅橡胶膜,并通过其在乙醇/水溶液中的溶胀实验,考察了制得的填充膜在乙醇/水溶液中的溶胀特性,讨论了不同ZSM-5分子筛填充量、乙醇/水质量分数及不同温度等因素对ZSM-5分子筛填充硅橡胶膜的溶胀度和溶胀选择因子的影响. Polydimethysiloxane (PDMS) membranes filled with ZMS- 5 zeolite were prepared by solution blending method. The swelling characteristics of the zeolite filled PDMS membranes dipped in ethanol - water solutions were investigated by a series of experiments. The effects of the filled content of ZSM - 5 zeolit, the ratio of ethanol water, and temperature on swelling ratios (SR) and swelling selectivity factors (as) of the ZMS - 5 zeolite filled PDMS membranes were discussed.
出处 《膜科学与技术》 CAS CSCD 北大核心 2009年第4期53-56,共4页 Membrane Science and Technology
基金 国家"973"项目(2003CB615701) 国家自然科学基金资助项目(20576059 20676067 20736003) 中石化科技开发研究基金(X505002) 中石油风险创新基金(05051143)
关键词 渗透蒸发 硅橡胶膜 ZSM-5分子筛 溶胀 pervaporation polydimethysiloxane (PDMS) rubber membrane ZSM - 5 zeolite swelling
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参考文献3

  • 1Leeper S A. Membrane separation in production of alcohol fuels by fermentation. Membrane separations in biotechnology[ M]. New York: Marcel - dekker, 1987.
  • 2Hennepe H J C, Bargeman D, Mulder M H V, et al. Zeolite filled silicone rebber membranes. Part 1. Membrane preparation and pervaporation results [ J ]. J Membr Sci, 1987,35 : 39 - 55.
  • 3Nguyen J Q. Modelling of influence of downstreampressure for highly pervaporation[J]. J Membr Sci, 1987,34. 165 - 172.

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