期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

PVA/Nb_2O_5复合碱性固体聚合物电解质的性能 被引量：1

Performance of PVA/Nb_2O_5 based composite alkaline solid polymer electrolyte
下载PDF
导出
摘要 以聚乙烯醇(PVA)、Nb2O5和KOH为原料,采用溶液浇铸法制备了PVA/Nb2O5复合碱性固体聚合物电解质(ASPE)。研究了Nb2O5对ASPE离子电导率(σ)和电化学稳定窗口的影响。交流阻抗和循环伏安的结果表明:加入15%Nb2O5的复合ASPE膜,室温σ为10.45 mS/cm,电化学稳定窗口为2.4 V。 PVA/Nb2O5 composite alkaline solid polymer electrolyte（ASPE）was prepared via solution casting method by using polyvinyl alcohol（PVA）, Nb2O5 and KOH as raw materials. The effects of Nb2O5 on ionic conductivity （σ） and electrochemical stability window of the ASPE were investigated. The results of AC impedance and cyclic vohammetry showed that the a at room temperature of the composite ASPE membrane adding 15% Nb2O5 was 10.45 mS/em,the electrochemical stability window was 2.4 V.
作者 陈忠元 居亚兰 朱云峰 李李泉
机构地区 南京工业大学材料科学与工程学院
出处 《电池》 CAS CSCD 北大核心 2009年第4期200-202,共3页 Battery Bimonthly
关键词 NB2O5 碱性聚合物电解质(ASPE) 离子电导率 电化学稳定窗口 Nb2O5 alkaline solid polymer electrolyte（ASPE） ionic conductivity electrochemical stability window
分类号 TM912.2 [电气工程—电力电子与电力传动]
  • 相关文献

参考文献9

  • 1王以存,张文锋,朱云峰,李李泉.加镍球磨对氢化燃烧合成Mg_2NiH_4的影响[J].电池,2008,38(6):343-345. 被引量：7
  • 2Yang C C. Polymer Ni-MH battery based on PEO-PVA-KOH polymer electrolyte[J]. J Power Sources,2002,109 ( 1 ) : 22 - 31.
  • 3Vassal N, Salmon F, Fauvarque J F. Electrochemical properties of an alkaline solid polymer electrolyte based on P(ECH-co-EO) [ J]. Electrochim Acta,2000,45(8 - 9) : 1 527 - 1 532.
  • 4Wu G M, Lin S J, Yang C C. Preparation and characterization of PVA/PAA membranes for solid polymer dectrolytes[J]. J Membr Sci,2006,275(1-2) : 127 - 133.
  • 5Yuan A B,Zhao J. Composite alkaline polymer electrolytes and its application to nickel-metal hydride batteries[J]. Electrochim Acta,2006,51(12):2 454-2 462.
  • 6吴锋,毛立彩.碱性电池用准固态聚合物电解质膜[J].电池,2005,35(5):335-337. 被引量：5
  • 7Wieczorek W, Such K, Florjanczyk Z, et al. Polyether polyacrylamidc, LiClO4 composite electrolytes with enhanced conductivity [J]. J Phys Chem, 1994,98(27):6 840- 6 850.
  • 8Sang S B,Zhang J F, Wu Q M, et al. Influences of Bentonite on conductivity of composite solid alkaline polymer electrolyte PVA- Bentonite-KOH-H2O[J]. Electrochim Acta,2007,52(25) :7 315 - 7 321.
  • 9CAOChu-nan(曹楚南) ZHANGJian-qing(张鉴清).电化学阻抗谱导论[M].Beijing(北京):Beijing Science Press(北京科学出版社,2002..

二级参考文献14

  • 1巴志新,柳东明,李李泉.镁的氢化反应对氢化燃烧合成储氢合金Mg_2NiH_4纯度的影响[J].材料科学与工程学报,2004,22(4):539-543. 被引量：7
  • 2袁华堂,邹雅冰,王一菁,乔林军,高秀玲.MgNi-NiB合金的制备与性能研究[J].电池,2005,35(4):254-255. 被引量：3
  • 3柳东明,韦涛,李李泉.氢化燃烧合成Mg-Mg_2Ni储氢合金组成和性能研究[J].材料科学与工程学报,2005,23(6):818-821. 被引量：4
  • 4韩晓英,张羊换,王新林,王国清.球磨镁基贮氢合金的研究[J].电池,2006,36(3):170-172. 被引量：7
  • 5Liu D M, Zhu Y F, Li L Q.Crystal defect analysis and surface characteristics of Mg2NiH4 produced by hydriding combustion synthesis[ J]. Int J Hydrogen Energy, 2007, 32 ( 13 ) : 2 417 - 2 421.
  • 6Liu X F, Zhu Y F, Li L Q.Hydriding characteristics of Mg2Ni prepared by mechanical milling of the product of hydriding combustion synthesis[J]. Int J Hydrogen Energy, 2007,32 (13) : 2 450 - 2 454.
  • 7Zhang Y, Lei Y Q, Chen L X, et al. The effect of partial substitution of Zr for Ti on the electrechemical properties and surface passivation film of Mg35T10-xZrxNi55(x = 1,3,5,7,9) electrode alloys[J]. J Alloys Compd,2002,337(1- 2) :296 - 302.
  • 8Horikiri H, Kato A, Inoue A, et al. New Mg-based amorphous alloys in Mg-Y-misch metal systems[J] .Mater Sci Eng, A, 1994,179 - 180:702 - 706.
  • 9衣宝廉 邵志刚.新能源材料[M].天津:天津大学出版社,2000.174-191.
  • 10Mohri M, Tajima Y, Tanaka H, et al. Rechargeable batteries with hydrogen storage alloys [J] .Sharp Technical Journal, 1986, 34:97 -102.

共引文献14

同被引文献13

  • 1吴玲丽,王世忠,梁营.La0．9Sr0．1Ga0．8Mg0．2AlxO3-δ（x=0～0．05）电解质电导率的研究[J].电池,2006,36(6):429-431. 被引量：1
  • 2Fenton D E,Parker J M,Wright P V,et al.Complexe ofalkali metal ions with poly(ethytlene oxide)[J].Polymer,1973,14:589-591.
  • 3Arunima Saxena,Arvind Kumar,et al.Preparation andcharacterization of N-methylene phosphonic and quatern-ized chitosan composite membranes for electrolyte separa-tions[J].Journal of Colloid and Interface Scien,2006,303:484-493.
  • 4Ying Wan,Katherine A M Creber,et al.Chitosan-based elec-trolyte composite membranes I.Preparation and Characteriza-tion[J].J.Membrane Science,2006,280:666-674.
  • 5M Z A Yahya,A K Arof,et al.Effect of oleic acid plasti-cizer on chitosan-lithium acetate solid polymer electrolytes[J].European Polymer Journal,2003,39:897-902.
  • 6Ying Wan,Katherine A M Creber,et al.Chitosan-basedelectrolyte composite membranes II.Mechanical propertiesand ionic conductivity[J].J.Membrane Science,2006,284:334-331.
  • 7L S Ng,A A Mohamad,et al.Protonic battery based on aplasticized chitosan-NH4NO3 solid polymer electrolyte[J].J.Power Source,2006,163:382-384.
  • 8Chun Chen Yang.Chemical composition and XRD analysesfor alkaline composite PVA polymer electrolyte[J].Mate-rials Letters,2003,58:33-38.
  • 9R H Y Subbaw,A K Arof,et al.Polymer batteries withchitosan electrolyte mixed with sodium perchlorate[J].Material Science&Engineering B,1996,38:156-160.
  • 10M J Rice,W L Roth.Ionic transport in super ionic con-ductors:a theoretical model[J].Journal of Solid StateChemistry,1972,4(2):294-310.

引证文献1

电池
2009年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部