摘要
合成了一种具有整形结构的反式－９，１０－二氢－９，１０－二苯基－９，１０－菲二醇（１）作为主体分子，它能与许多有机小分子化合物，诸如ＤＭＦ，ＤＭＳＯ，吡啶，哌啶，喹啉，异喹啉等包结化合物，本文还报道了这些包结化合物的ＩＲ，粉末ＸＲＤ的表征，用ＨＮＭＲ测定了它们的分子摩尔比，ＤＭＦ包结物的单晶四圆Ｘ衍射结果表明主体分子１与客体分子形成的包结物为配位笼状包合物。
A compoumd having chela shape, trans-9, 10-dihydro-9, 10-diphenyl phenanthrene- 9,10 - diol(1), was synthesized. It could form the inclusion compounds with various small organic molecules such as DMF, DMSO, pyridine, piperidine, quinoline isoquinline. These inclusion compounds were confirmed by means of IR and powder XRD, and their host-guest molar ratio was determined by 1H NMR. The results of four circle XRD for single cyrstal of the inclusion compound of the host molecule (1) with DMF shown that the host molecule(1)formed coordinatoclathrate with guest molecules.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1998年第8期812-818,共7页
Acta Chimica Sinica
基金
国家自然科学基金(39370810)
关键词
反式
二氢
二苯基
菲二醇
包结化合物
配位笼状
trans - 9,10 - dihydro - 9,10 - diphenyl phenanthrene - 9,10 - diol, inclusion compounds, coordinatoclathrate, X- ray diffraction
