摘要
通过能量为100keV,剂量为1×1018cm-2的N+注入到硅基体中,经1000~1200℃之间快速退火后,形成了含氧的硅与氮化硅镶嵌结构的薄膜层.在室温下观测到主要来自于45nm表面层的能量分别为:3.3eV、3.0eV、2.8eV和2.2eV的光致发光.通过XPS、AES的分析,确认了由于氧的插入,样品中N-Si-O缺陷,Si/SiO2界面发光中心,分别是引起3.0eV和2.2eV的光致发光的主要原因.
Abstract Si 3N 4 nanoparticles embedded in Si film is formed by nitrogen ion implanted into Si wafers with high dose (1×10 18 cm -2 ) followed by a Rapid Thermal Annealing (RTA) (1000~1200℃). And four emission bands are observed, corresponding to 3 3eV, 3 0eV, 2 8eV and 2 2eV, respectively. Our experiment results demonstrate that silicon dangling band, defect state of N Si O and Si/SiO 2 interfaces play a dominant role in the PL spectra.